WPCz 1Dtb2%+'p&,Qi0otiz3M~Z#Z /uˍSF-X%u,/Sf1kυz@ &C5&q1ܝpI5ĦҔ{њ]~F18k@`e&P6]*XtH)_1|4#t3 $$!Lm!0X,X"pD{͜[!# D8(Ƥ>xCz uHBI,ճم0@0a[1 hGo15 h6;f;a;f;a;f;a;;f="=a'>;> h[J? h@ hA hyBHGCC hl=D hJ h,K h M h*N h%U h \ h] h_` h{b hzg hll hppppppppppppppppppppppptttttttt5uuUHvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvvwwUHxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxyUHzHP LaserJet Series IIHPPCL,hh,0 / + AZ0Univers (W1) Regular&(#$      C:\OFFICE\WPWIN\TEMPLATE\STANDARD.WPT VDVVDVVDVVDV/V/V/9["O 3|xVC:\OFFICE\WPWIN\TEMPLATE\STANDARD.WPT;/O Z$Symbol Regular(?3$ !       TABLE ELevel 1Level 2Level 3Level 4Level 5Level 1Level 2Level 3Level 4Level 5Level 1Level 2Level 3Level 4Level 5Level 1Level 2Level 3Level 4Level 5Level 1Level 2Level 3Level 4Level 5 d& d d+ +dX XdTABLE Ad  '       XeX&&CYTECTITLEVPERMIT  ԀREMEDIALACTIVITY tԀSECTION(contd.)#&&XXeA# H   x   ` ?(#&&June6,1997#&&*#\ $#&OLE 2.0 Box <=8C HKKKK(?3$ !        d'dxd( $ Figure  1  G H1C<< C(K3$ !        d (?3$ !       (?(3M$ !           0  (#$  0  (?3$ !         +M$        1    0 ` +&&USEPA,0` (#` (#Air/SuperfundNationalTechnicalGuidanceStudySeries:Modelsfor H EstimatingAirEmissionRatesfromSuperfundRemedialActions,EPA  451/R93001#&&+f#' dxd(Vm$0     '       XeX&&CYTECTITLEVPERMITEMISSIONSLIMITATIONSECTION(contd.)#&&XXeA#  H   '       XeX&&CYTECTITLEVPERMITEMISSIONSQUANTIFICATIONSECTION(contd.) #&&XXeA# H 5(,!$0  0` (#(#    '       CYTECTITLEVPERMIT H   PLANTWIDEAPPLICABILITYLIMITATION(PAL)SECTION(contd.) j (Vm$0    ;#M << deUU(n$ (  1  ) 3+0 d d d25  '       XeX&&TABLEOFCONTENTS(contd.) #&&XXeA# H   '       XeX&&LISTOFACRONYMS(contd.) H #&&XXeA# TABLE F(?3$ !       ($$   1  TABLE B>$"Small Circle"0  TABLE ATABLE BTABLE CTABLE D +M$        1    @Y&&ԀDerivedfromtestingperformedinaccordanceEPAapprovedmethods#&%&@YZ#(,!$0  0` (#(#     '       XeX&&CYTECTITLEVPERMITAPPLICABLEREQUIREMENTSSECTION#&&XXeA#XeX&&(contd.) #&&XXe# H   '       XeX&&CYTECTITLEVPERMITEMISSIONSMONITORINGSECTION(contd.) #&&XXeA# H 5   '       XeX&& CYTECTITLEVPERMITEMISSIONSUNITSSECTION #&&XXeA#XeX&&(contd.) #&&XXe# H   '     XeX&&  CYTECTITLEVPERMIT  PREAPPROVEDMODIFICATIONS uSECTION(contd.) H  #&&XXe5#C:\WINDOWS\STANDARD.WPT(hH  Z 6Times New Roman Regular>b$Large Circle0 (@$0  0` (#(#0 ` (#` (# ` TABLE AC:\WINDOWS\TEMPLATE\STANDARD.WPTC:\OFFICE\WPWIN\TEMPLATE\STANDARD.WPT  '     XeX&&  CYTECTITLEVPERMITLIKEKINDREPLACEMENTSECTION(contd.) #&&XXe5# H TABLE BTABLE BTABLE B(99Z 6Times New Roman RegularTABLE ATABLE G\   '       XeX&& CYTECTITLEVPERMITSITEDESCRIPTION #&&XXeA#XeX&&(contd.) #&&XXe# H TABLE G %   ?  ?  @  @  @  @  @  @  @  @  @  @  @  @  @  @  $@ $TABLE E   '     XeX&&  CYTECTITLEVPERMITPOLLUTIONPREVENTION(P2)SECTION(contd.)#&&XXe5#  H ;?@@@    ?   @      @@@ @ @ @p@@@@"@TABLE ATABLE ATABLE B\TABLE C   '       XeX&&CYTECTITLEVPERMITNOTIFICATIONSECTION(contd.)#&&XXeA#% %&& H  #&&%% #   '       XeX&& CYTECTITLEVPERMITEMISSIONSUNITSSECTION #&&XXeA#XeX&&(contd.) #&&XXe# H TABLE I   '     XeX&&  CYTECTITLEVPERMIT  REPORTINGREQUIREMENTS uԀSECTION(contd.) #&&XXe5# H T@j$@HTABLE G8 888?8QN@8@8QN@8@8QN@TABLE D8? ?????X9vN@?@?X9vN@?@?X9vN@TABLE C?@@@@@b@@@@R@@;@TABLE A@ > (+     d    '       AIRPOLLUTANTEMISSIONSESTIMATIONMETHODSFORREMEDIALACTIVITIES(contd.)  h EUEEEEEEEEEEEEEEEEEEE E E E E E E E E E EEEEEEEEEEEEEEEEEEEEEEEEE@EEEEEEEEEEEE E E!E!E"E"E#E#E$E$E%E%E&E&E'E'E(E(E)E)TABLE FEI III?II@II@ITABLE BIKKKKKKKK?KKK?KKKK{Gz?KKK{Gz?KKKKKKKKTABLE BK` ````````````TABLE B`a_aaaaa@aaaaaaaaaaaaaa a a a a a a a a a aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa a a!a!a"a"a#a#a$a$a%a%a&a&a'a'a(a(a)a)a*a*a+a+a,a,a-a-a.a.TABLE Aai<iiiiii0  0(#(#    III.0(#(#DEVIATIONS#`"`"I(#.  (#(##715!m>>݌ h Ќ  COMPLIANCESCHEDULES(ifnecessary)(#(#K(#.-   0 [Ifthereanycomplianceissues,thissectionwillbeprovidedalaterdate]    PERMITSHIELD(#(#K(#.    D t 5!  5!_@0  0(#(#    I.0(#(#NONAPPLICABLEREQUIREMENTS#(#(#K(#.FF*(#(##5!_@z@݌    Ќ  [Thissectionwillbeprovidedalaterdate]    APPENDIXA0 ` 0 ` (#` (#AIRPOLLUTANTEMISSIONSESTIMATIONMETHODSFORBATCH   PROCESSES  (# (# APPENDIXB0 ` 0 ` (#` (#AIRPOLLUTANTEMISSIONSESTIMATIONMETHODSFORREMEDIAL @p ACTIVITIES H (# (#  DC  XeX&&  LISTOFACRONYMS #&&XXe C# H )C*wEFddd Xdd Xdd X(#(#w, dd ,udd +  "  B"ACRONYM % %DESCRIPTION 4*! B0   B 4acfm %T   %actualcubicfeetperminute /%T  B0  B /ACT %J  %AlternativeControlTechniques /%J  B0  B /ASC %    %ActualStackConcentration /%   B0  B /BACT %    %BestAvailableControlTechnology /%   B0  B /cfm %L    %cubicfeetperminute /%L   B0  B/CFR % B  %CodeofFederalRegulations /% B  B0  B /CO %   %CarbonMonoxide /%  B0  B /CTG %   %ControlTechniquesGuideline /%  B0  B /DEP %D   %DepartmentofEnvironmentalProtection /%D  B0  B/dscf %: %drystandardcubicfeet /%: B0  B/dscm %x %drystandardcubicmeters /%x B0  B/EPA % %EnvironmentalProtectionAgency /% B0  B /FGR %<  %FlueGasRecirculation /%< B0  B /gph %z2   %gallonsperhour /%z2! B0  B /gpm %p"  %gallonsperminute /%p# B0  B/HAP %$ %HazardousAirPollutant /%% B0  B/HON %4& %HazardousOrganicNESHAP /%4' B0  B /LAER %r*(  %LowestAchievableEmissionRate /%r*) B0  B/MACT %h* %MaximumAchievableControlTechnology /%h+ B0  B/MASC %, %MaximumAllowableStackConcentration /%- B0  B/MON %, . %MiscellaneousOrganicNESHAP /%, / B0  B/NESHAP %j!"0 %NationalEmissionStandardsforHazardousAirPollutants /%6"2 B0  B /NOX %t#, 3  %NitrogenOxides /%t#, 4 B0  B /NSR %$j!5  %NewSourceReview /%$j!6 B0  B /OAQPS %%"7  %OfficeofAirQualityPlanningandStandards /%%"8 B0  B /P2 %.'#9  %PollutionPrevention /%.'#: B0  B /PAL %l($%;  %PlantwideApplicabilityLimitation /%l($%< B0  B /PCD %)b&=  %PollutionControlDevice /%)b&> B0  B /ppmv %*'?  %partspermillion,volumetricbasis /%*'@ B0  B /ppmw %&,(A  %partspermillion,weightbasis /%&,(B B0  B /PTE %d-*C  %PotentialtoEmit 3) d-*D B0  B3RACT %PB %ReasonableAvailableControlTechnology /%PB B0  B/RCSA % %RegulationsofConnecticutStateAgencies /% B0  B /SIP %   %StateImplementationPlan /%  B0  B /SOCMI %   %SyntheticOrganicChemicalManufacturingIndustry /%  B0  B/TOC %H :  %TotalOrganicCarbon /%H :  B0  B/tph % x  %tonsperhour /% x  B0  B/tpy %  %tonsperyear /% B0  B /TSP %  %TotalSuspendedParticulate /% B0  B/VOC %@2  %VolatileOrganicCompound /%@2  B0  B /VOL %~p   %VolatileOrganicLiquid," ~p  B0 )  ,  zl  МDr  7&&d&&d7   XeX&& CYTECTITLEVPERMITSITEDESCRIPTION  H  W#&&XXeW# I.PURPOSE   ThepurposeofthissectionistodescribethemanufacturingactivitiesattheCytecWallingfordsite,andtopresentthepotentialandactualemissionsinventoryforallregulatedairpollutantsemitted. II.BACKGROUND   `  Cytecisaresearchbasedchemicalcompanywhichdevelopsandmanufacturesproprietaryproductsandtechnology.Cytecdevelops,manufacturesandmarketsspecialtychemicals,specialtymaterials,andbuildingblockchemicals,servingabroadgroupofendusers,includingthewatertreatment,paper,mining,coatings,plastics,aerospaceandautomotiveindustries.CytecoperatessitesintheUnitedStates,GreatBritain,Netherlands,CanadaandMexico.XeX&&mX XXXeԀ#XeX XmX[##&&XXex[# H  Approximately600peopleareemployedattheWallingfordsite.Thesiteislocatedon250acresextendingfromtherailroadmainlineontheeasttotheQuinnipiacRiveronthewest.Itcomprises32buildings,twomilesofstreetsandroadsandtotals3.2milesarounditsperimeter.TheprimaryactivitiesconductedatthesiteareclassifiedundertheStandardIndustrialClassification(SIC)codeof2821.TheWallingfordsite,consideredcriticaltoCytecscorebusiness,manufacturesthreedistincttypesofproductsfromthreeseparateproductiondepartments.Thecategoriesofproductsmanufacturedatthesiteare:8  ^b  ^b^0!!  Thermosetmoldingcompounds^b^^݌,!! Ќ  8  ^b  ^bU_0!!  Thermoplasticmoldingcompounds^bU_p_݌|!! Ќ  8  ^b  ^b`0!!  Liquidandspraydriedresins^b`0`݌\!! Ќ  TheWallingfordPlantopenedin1941fortheproductionofthermosetmoldingcompoundsandthisfunctionstillinvolvestheplant'sgreatestconcentrationofmanpower.ThisbusinessunitiscalledACMoldingCompounds.ItisajointventurebetweenCarmelChemicalCompanyandCytecIndustriesInc.ThisproductlineconsistsoftwotypesofmoldingcompoundsdesignatedasBEETLEandCYMEL.8  ^b  ^b^b0!!  BEETLEproductsareusedinmoldingbuttons,bottlecaps,andsuchelectricalfixtures "t' aswallplates,sockets,plugsandcircuitbreakers.^b^byb݌ !! Ќ  8  ^b  ^bc0!!  CYMELproductsareusedindecoratedandundecorateddinnerware,sinks,ashtrays,  %!* andhandlesforkitchenutensils.^bcc݌ !! Ќ  Thermoplasticoperationsbeganin1956andhavegrownsteadilysince.ThisbusinessunitiscalledCYROIndustries.ItisajointventurebetweenRohmIndustriesandCytecIndustriesInc.AvarietyofeverydayproductsaremanufacturedwithCYRO'sthermoplasticmaterial,includingautomobiletaillights,instrumentpanelcovers,batterycasesanddecorativetrimforawidevarietyofuses.Italsoiswidelyusedinthefoodpackagingindustryforsuchthingsasplastictubsformargarine,blisterpacksforcrackersandcookies,crispertraysandbuttercompartmentsinrefrigerators.Otherusesincludefishingtackleboxesandtrays,artificiallures,pianokeysandtoys.Somematerialis manufacturedaslargesheetsandthenfabricatedintosigns,greenhouses,solarpanelcoverings -)4 andwindowanddoorglazing.Inaddition,averyhighgradematerialisusedinthemedicalfieldtoproducevariousdevicesfortransferandpurificationofblood. TheResinsDepartmentbeganoperationsin1943andtodayproducesseveralproductlinesevidentindailylife.Paperproductresinsaddwetordrystrengthpropertiesandincreasetheabsorbanceofsuchpaperitemsasbags,towels,tissues,maps,moneyanddisposaldiapers.Cytec'slaminatedresinsareusedtoproducebeautifulhardsurfacesforcountertops,cabinetsandfurniture,whiletextileresinsgivetoday'sclothingitswrinkleandwaterresistanceanditspermanentpresscharacteristics.Methylatedresinsprovideautomotiveandappliancemanufacturerswithmorecosteffectivecoatingsforfinishingtheirproducts.Besidesthethreemanufacturingareas,Cytecoperatesawastewatertreatmentplantthattreatseffluentfromthethreemanufacturingareas,andaboilerhousethatsuppliessteamtoallpartsofthesite. III.EMISSIONSINVENTORY  l$ r  Cytecstipulatesthatitisamajorsourceofthefollowingairpollutants:0  ^b  ^bl0(#(#  CarbonMonoxide^bll݌`(#(# Ќ  0  ^b  ^bDm0(#(#  HazardousAirPollutants^bDm_m݌t,(#(# Ќ  0  ^b  ^bm0(#(#  NitrogenOxides^bmn݌@(#(# Ќ  0  ^b  ^bn0(#(#  ParticulateMatter/PM10^bnn݌ (#(# Ќ  0  ^b  ^bho0(#(#  SulfurDioxide^bhoo݌(#(# Ќ  0  ^b  ^bp0(#(#  VolatileOrganicCompounds^bp1p݌\(#(# Ќ  ThefollowingtablepresentstheactualemissionsfromtheCytecWallingfordsiteforcalendaryear1996.[Tobedevelopedpriortopermitissuance.]  X! Y  XeX&&  CYTECTITLEVPERMITEMISSIONSUNITSSECTION #&&XXeq#  H q I.PURPOSE   ThepurposeofthissectionistolisttheemissionsunitspresentatCytec,anddescribetheapplicablerequirements,controlequipment,monitoringequipment,andcompliancestatuswithrespecttoeachemissionsunit. II.LISTOFEMISSIONSUNITSANDCONTROLEQUIPMENT  t ,  [Note:Thereareapproximately40emissionunitscurrentlypresentatCytec.Onlyoneoftheseisincludedbelowtoserveasanexample.]   ThefollowingtableliststheemissionsunitspresentattheCytecWallingfordsite,includingthecontrolequipmentassociatedwitheachemissionsunit.&&*fpd*d dd udd EF(#(#f,Xdd ,dd ,Sdd ,dd ,dd ,dd ,Edd +  ""  UNITID '"""" 'UNITNAME '"""" 'UNITDESCRIPTION '""<"" 'PERMIT/REGIST.NO. '""L"" 'CONTROLID '"""" 'CONTROLNAME +""""" +CONTROLDESCRIPTION )""" """ )C06 )"""!""" )CyroTolueneRecoverySystem )"""%""" )Thissystemrecoversthetoluenevolatilizedintheextrudersandpurifiesthesolventinpreparationforitsreuse.Equipmentincludesdecanters,recoveredmaterialstoragevessels,condensers,sealpots,andthecarbonadsorptionunit. )"""D0""" )R0213,R0233 )"""82""" )10CA6046 )"""3""" )CyroCarbonAdsorptionUnit +"""",6""" +CarbonAdsorption(048).Twochamberunit,inwhichoneactivatedcarbonbedadsorbswhiletheotherisregeneratedusingsteam.&4?  """" &&& III.MONITORINGEQUIPMENT  A ThefollowingtabledescribesthemonitoringdevicesusedtoconfirmpropercontrolequipmentoperationattheCytecWallingfordsite.&&*qsddXdd dd Sdd dd dd dd Edd p(#(#,edd ,dd ,dd ,4dd ,1dd +  "" "F  CONTROLID '""l"$G"" 'CONTROLNAME '""#I"" 'MONITORID '""#K"" 'MONITORNAME +"""l"$L"" +PARAMETERMEASURED 0""!l"$M  """ 010CA6046 8"")'%!O"" 8CyroCarbonAdsorptionUnit '""%!Q"" '10CAT1 '""X$!R"" 'CarbonAdsorberThermocouple +"""%!T"" +Temperatureofgasventedintocarbonadsorber +""%!V""" + *""%"V"" *CyroCarbonAdsorptionUnit '""&#X"" '10CAT2 '""D&"Y"" 'CarbonAdsorberSteamRegenerationCondenserThermocouple +"""'T$\"" +Temperatureofcoolingtowerwaterfedtocondenser +""&#^""" + *""x(0%^"" *CyroCarbonAdsorptionUnit '"")@&`"" '10CAF1 '""(%a"" 'CarbonAdsorberContinuousAirFlowMeter +""")@&c"" +Volumetricairflowrateofgasventedintocarbonadsorber )"""4*&f""" )10CA6046cont. )""" ,(h""" )CyroCarbonAdsorptionUnit )""" ,(j""" )10CASC1 )"""t+,(k""" )CarbonAdsorberStripChartRecorder +"""" ,(m""" +Durationofbedadsorptioncycles& ,(o  """" &&& -*p  IV.EMISSIONSUNITAPPLICABLEREQUIREMENTSANDCOMPLIANCESTATUS   Thefollowingtabledescribetheregulatoryrequirementsassociatedwitheachemissionsunit,andthemethodofdeterminingcomplianceandcompliancestatuswithrespecttoeachrequirement.&&*"ddedd dd dd 4dd 1dd qs(#(#,Xdd ,dd ,dd ,dd ,dd ,dd +     UNITID    REGULATORYCITE     REGULATORYDESCRIPTION     REQUIREMENT   L  COMPLIANCEMETHOD    COMPLIANCESTATUS    C06 & 8@@g0 &RCSA22a1742   8 SourceRegistration    Obtainregistrationnumber    Notapplicable.   8 Incompliance   8     RCSA22a17420(a)   ControlofVOCfromLiquidStorageVessels  L|  Maintainrecordsoftankcapacityandvaporpressureoforganicmaterialcontents.  P # Notapplicable.   $$ Notapplicable.Storagevesselsare<40,000galorvaporpressureis<1.5psi.   )   ,\ ) RCSA22a17420(c)  <l + ControlofVOCfromWastewaterSeparators  . Maintainrecordsoforganicmaterialvaporpressureand,if>1.5psi,organicmaterialthroughput.  4 Notapplicable.   5 Notapplicable.Wastewaterdecantersreceive<200gpdorganicmaterialorvaporpressure<1.5psi.  ;   ; RCSA22a17420(ee)  = VOCRACTOrder  ,\> ReduceuncontrolledVOCemissionsventedtothecarbonadsorberbyatleast85percent.  D Stacktest  ,\E Incompliance.Stacktestdataindicatesgreaterthan95percentcontrol.   J   dJ BatchProcessesACT  tL BatchProcessesAlternativeControlTechniques   PO ReduceventeduncontrolledVOCemissionsby90percentifcosteffective.  xT Calculateifcosteffective(seeApplicableRequirementsSection)andevaluatecontrolefficiency(seeEmissionslimitationSection)  (!X] Incompliance.  ^ C06cont. &#D` 7 &RCSA22a17429  h"a ControlofHazardousAirPollutants  #d EmissionsofTable291compoundsmustnotexceedMASC.  l$h Emissioncalculations  #Dj Incompliance.  h"k   H%xk 40CFR60SubpartKb  X& m StandardsofPerformanceforVOLStorageVessels  '!q Maintainrecordsoftankcapacityandcontentsvaporpressure.  '!u Notapplicable.  %v NotApplicable.Storagevesselsare<151m3or '4!y vaporpressure<15.0kPa. \("{  &&  *%} UY  XeX&&  CYTECTITLEVPERMITAPPLICABLEREQUIREMENTSSECTION#&&XXe#  H [Note:IfthePart70ruleandConnecticutsTitleVregulationarerevisedsuchthatapplicable  requirementscanbeincorporatedintothispermitwithouttheneedforasignificantpermitmodification,thenthissectionmaybecomelargelyunnecessary.] h ̜ I.PURPOSE  P ̜ThepurposeofthissectionistodescribetheapplicablerequirementsCytecisormayreasonablybeanticipatedtobesubjectto,theoptionsCytecwillemploytocomplywiththeseapplicablerequirements,andtoprovidealternativemethodsofcompliance,suchasaVOCRACTemissionsaveragingmechanism.RequirementsidentifiedinthissectionthatbecomeapplicableasaresultofmodificationsthatoccuratCytecwillbeincorporatedintothispermitusingtheminorpermitmodificationprocedure.Requirementsnotidentifiedinthissectionthatbecomeapplicableduringthefirsttwoyearsofapermittermwillbeincorporatedintothispermitusingtheappropriatepermitmodificationprocedure.IfConnecticutdoesnotamendRCSA22a17433toincludeaminorpermitmodificationprocedure,thenpriortopermitissuanceallpossibleapplicablerequirements,includingbutnotlimitedtothoselistedbelow,willbeincorporatedintothispermit.[NotethatthetimeframescorrespondingtosubmissionofanapplicationtomodifytheTitleV p operatingpermit,andattainmentofcompliancewiththeunderlyingapplicablerequirement,areinpartdependentonthespecificapplicablerequirementandwillbedevelopedpriortopermitissuance.] 4 ̜ II.APPLICABLEREQUIREMENTS  X ThefollowingtableliststheStateandFederalairregulations,indicatingwhichapplyandwhichdonotapply.Abriefexplanationisprovidedforthoseregulationsthatdonotapply.[Tobedevelopedpriortopermitissuance.] `  III.40CFR63REQUIREMENTS  ! (a)  40CFR63SubpartB(112(g)MACTdeterminations) p#   (i)0  PurposeP!%(#(# 0  IfCytecconstructsorreconstructsitsoperationsinawaythattriggerstherequirementforreviewϜpursuanttoregulationsimplementingtherequirementsofsection112(g)oftheCleanAirAct,thissubsectionofthepermitisdesignedtoincorporatecompliancetermsthatwillimplementMACTfortheconstructionorreconstructionwithoutrequiringasignificantpermitrevisionifEPAhasproposedaMACTstandardthatisapplicabletotheproposedchange.AlltermsinthisprovisionshallhavethesamemeaningasintheregulationsimplementingtherequirementsofϜsection112(g)whereapplicable. (#(#   (ii)0  ApplicabilityH)&/(#(# 0  ThisprovisionshallbeavailableforanymajornewsourceormajorreconstructionofHAPsforϜwhichcompliancewiththeMACTdeterminationcanbedeterminedusingthequantificationandmonitoringsectionsofthispermitoranyreplicablemonitoringrequirementsintheproposedMACTstandard.#D-)4(#(#7 #Ї  (iii)0  MACTDetermination(#(# 0  CytecmayuseaMACTstandardapplicabletotheconstructionorreconstructionthathasbeenformallyproposedintheFederalRegisterasthebasisfortheMACTdetermination,providedthe 4d proposedMACTstandarddoesnotrequireacasebycasepermitreviewtodetermineappropriatecomplianceconditionsatsubjectfacilities.Wheretheproposedstandardincludesbothspecificlimitsandcompliancerequirementsandalternativecomplianceoptionsbasedonacasebycasereview,CytecshallcomplywiththespecificlimitsandcompliancerequirementsintheproposedMACTstandard. (#(# 0  IfthereisnoproposedMACTstandardorifCytecchoosestodemonstrateaMACTlevelofcontrolinsomeothermanner,DEPorEPAwillperformacasebycaseMACTdeterminationforthemodification.TheMACTdeterminationresultsshallbeincorporatedintotheapplicablerequirementssectionofthispermitusingtheappropriateTitleVpermitmodificationprocedure. (#(# (b)MACTStandards  (i)0  CurrentlyApplicable\ (#(# 0  CytecisnotcurrentlysubjecttoanyMACTstandards. (#(#   (ii)0  FutureApplicable(#(# 0  CytecmayreasonablybeanticipatedtobecomesubjecttothefollowingMACTstandards: (#(# 0    (A)0` (#(#40CFR63SubpartsFthroughI(HONrule)` (#` (# 0  0(#(#ShouldCytecbecomesubjecttothehazardousorganicsNESHAP,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR63.100and40CFR63.110,Cytecshalltakethefollowingcomplianceactions: (#(# 0     ` (1)0 (#(#Cytecshallcomplywiththeprocessventprovisionsspecifiedin63.113  through63.118;  (# (# 0     ` (2)0 (#(#Cytecshallcomplywiththestoragevesselprovisionsspecifiedin63.119  L! through63.123;  (# (#   0   ` (3)0 (#(#Cytecshallcomplywiththetransferoperationprovisionsspecifiedin63.126 !# through63.130;  (# (#     0 ` (4)0 ` (#` (#Cytecshallcomplywiththewastewaterprovisionsspecifiedin63.131 L#|% through63.147;  (# (#   0   ` (5)0 (#(#Cytecshallcomplywiththeleakinspectionprovisionsspecifiedin63.148.$' (# (# 0  0(#(#ShouldCytecseektousetheemissionsaveragingprovisionsspecifiedin63.150through63.152,theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(#     (B)0 ` 40CFR63SubpartUPolymers&ResinsI)#-` (#` (# 0  0(#(#ShouldCytecbecomesubjecttoSubpartU,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR63.480,Cytecshalltakethefollowingcomplianceactions: (#(# 0     ` (1)0 (#(#Cytecshallcomplywiththestoragevesselprovisionsspecifiedin63.484;-'2 (# (#   0   ` (2)0 (#(#Cytecshallcomplywiththecontinuousfrontendprocessventsprovisions  specifiedin63.485;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththebatchfrontendprocessventsprovisions h specifiedin63.486;  (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththebackendprocessoperationsprovisionsspecified  0 in63.487;  (# (#   0   ` (5)0 (#(#Cytecshallcomplywiththewastewaterprovisionsspecifiedin63.488;  (# (#     0 ` (6)0 ` (#` (#Cytecshallcomplywiththeequipmentleaksprovisionsspecifiedin63.489;d  (# (# 0     ` (7)0 (#(#Cytecshallcomplywiththeadditionaltestmethodsandprocedures 0 ` provisionsspecifiedin63.491;  (# (#   0   ` (8)0 (#(#Cytecshallcomplywiththemonitoringlevelsandexcursionsprovisions    specifiedin63.492;  (# (#     0 ` (9)0 ` (#` (#Cytecshallcomplywiththegeneralreportingandrecordkeeping `  requirementsprovisionsspecifiedin63.493.  (# (# 0  0(#(#ShouldCytecseektousetheemissionsaveragingprovisionsspecifiedin63.490,theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(# 0    (C)0` (#(#40CFR63SubpartJJJPolymers&ResinsIV$` (#` (# 0  0(#(#ShouldCytecbecomesubjecttoSubpartJJJ,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR63.1310,Cytecshalltakethefollowingcomplianceactions: (#(# 0     ` (1)0 (#(#Cytecshallcomplywiththestoragevesselprovisionsspecifiedin63.1314;  (# (#   0   ` (2)0 (#(#Cytecshallcomplywiththecontinuousprocessventsprovisionsspecifiedin  63.1315through63.1320;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththebatchprocessventsprovisionsspecifiedin T 63.1321;  (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththeheatexchangesystemsprovisionsspecifiedin  63.1328;  (# (#   0   ` (5)0 (#(#Cytecshallcomplywiththeprocesscontactcoolingtowersprovisions  specifiedin63.1329;  (# (#     0 ` (6)0 ` (#` (#Cytecshallcomplywiththewastewaterprovisionsspecifiedin63.1330; L! (# (# 0     ` (7)0 (#(#Cytecshallcomplywiththeequipmentleaksprovisionsspecifiedin63.1331; " (# (#   0   ` (8)0 (#(#Cytecshallcomplywiththeadditionaltestmethodsandprocedures !# provisionsspecifiedin63.1333;  (# (#     0 ` (9)0 ` (#` (#Cytecshallcomplywiththeparametermonitoringlevelsandexcursions L#|% provisionsspecifiedin63.1334;  (# (# 0     ` (10)0 (#(#Cytecshallcomplywiththegeneralreportingandrecordkeeping $' requirementsprovisionsspecifiedin63.1335.  (# (# 0  0(#(#ShouldCytecseektousetheemissionsaveragingprovisionsspecifiedin63.1332,theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(# 0  [ThefollowingMACTstandardswillbeincorporatedintothissectionifproposedorpromulgated x*$. priortopermitissuance.ProposedMACTstandardsaddressedinthissectionmaybeincorporatedintothepermitusingaminorpermitmodificationifthefinalMACTstandarddoesnotsubstantiallychangefromtheproposedMACTstandard.],$'1(#(#  -'2 0    (D)0` (#(#40CFR63Subpart___Polymers&ResinsIII` (#` (# 0    (E) ` 40CFR63Subpart___MONruleh(#(# 0  0(#(#(F)0` (#(#40CFR63Subpart___StationaryInternalCombustionEngines 0` (#` (# 0  0(#(#(G)0` (#(#40CFR63Subpart___IndustrialBoilers ` (#` (#     (I)0 ` 40CFR63Subpart___SiteRemediation0 `` (#` (# ̜ IV.40CFR60REQUIREMENTS    (a)NewSourcePerformanceStandards  (i)0  CurrentlyApplicable (#(# 0  Cytecissubjecttothefollowingnewsourceperformancestandards: (#(# 0    (A)0` (#(#40CFR60SubpartKbStandardsofPerformanceforVolatileOrganicLiquid 0 StorageVessels ` (#` (# 0  0(#(#RefertotheemissionsunitsandnotificationsectionsofthispermitforadescriptionofspecificSubpartKbrequirements. (#(# 0  (ii)0(#(#FutureApplicable(#(# 0  Cytecmayreasonablybeanticipatedtobecomesubjecttothefollowingnewsourceperformancestandards: (#(# М    0  0(#(#(A)ShouldCytecbecomesubjecttoSubpartDc,asdefinedintheapplicabilitycriteriaspecifiedin40CFR60.40c,Cytecshalltakethefollowingcomplianceactions: (#(#      ` 40CFR60SubpartAGeneralProvisions0  0(#(#0` (#(#(1)0 ` (#` (#Cytecshallcomplywiththenotificationprovisionsspecifiedin60.7(a)(1) "$ through(4);  (# (# 0  0(#(#0` (#(#(2)0 ` (#` (#Cytecshallcomplywiththestandardsandmaintenancerequirements $$T& specifiedin60.11(d).  (# (# Л  0  0` (#(#40CFR60SubpartDcStandardsofPerformanceforSmallIndustrialCommercialInstitutionalSteamGeneratingUnits ` (#` (# 0  0(#(# (#(# 0     ` (1)0 (#(#Cytecshallcomplywiththestandardforsulfurdioxideprovisionsspecified (#, in60.42c;  (# (#   0   ` (2)0 (#(#Cytecshallcomplywiththestandardforparticulatematterprovisions *$. specifiedin60.43c;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththecomplianceandperformancetestmethodsand ,L&0  proceduresforsulfurdioxideprovisionsspecifiedin60.44c;,'1 (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththecomplianceandperformancetestmethodsand   proceduresforparticulatematterprovisionsspecifiedin60.45c;  (# (#   0   ` (5)0 (#(#Cytecshallcomplywiththeemissionmonitoringforsulfurdioxideprovisions h specifiedin60.46c;  (# (#     0 ` (6)0 ` (#` (#Cytecshallcomplywiththeemissionmonitoringforparticulatematter  0 provisionsspecifiedin60.47c;  (# (# 0     ` (7)0 (#(#Cytecshallcomplywiththereportingandrecordkeepingrequirements   provisionsspecifiedin63.48c;  (# (# М0  0(#(#(B)ShouldCytecbecomesubjecttoSubpartKb,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR60.110b,Cytecshalltakethefollowingcomplianceactions: (#(# М     ` 40CFR60SubpartAGeneralProvisions0  0(#(#0` (#(#(1)0 ` (#` (#Cytecshallcomplywiththenotificationprovisionsspecifiedin60.7(a)(1) (  through(4);  (# (# 0  0(#(#0` (#(#(2)0 ` (#` (#Cytecshallcomplywiththestandardsandmaintenancerequirements   specifiedin60.11(d).  (# (#     0 ` 40CFR60SubpartKbStandardsofPerformanceforVolatileOrganicLiquidStorageVessels ` (#` (# Л0     ` (1)0 (#(#Cytecshallcomplywiththeemissionstandardprovisionsspecifiedin X 60.112b;  (# (#   0   ` (2)0 (#(#Cytecshallcomplywiththetestingandproceduresprovisionsspecifiedin   60.113b;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththereportingandrecordkeepingprovisionsspecified  in60.115b;  (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththemonitoringofoperationsprovisionsspecifiedin  P 60.116b;  (# (#   0  0(#(#ShouldCytecseektousethealternativemeansofemissionlimitationprovisionsspecifiedin60.114b,theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(#     0  (C)0` (#(#40CFR60SubpartVVStandardsofPerformanceforEquipmentLeaksofVOCin !# theSyntheticOrganicChemicalsManufacturingIndustry ` (#` (# 0  0(#(#ShouldCytecbecomesubjecttoSubpartVV,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR60.480,Cytecshalltakethefollowingcomplianceactions: (#(#      ` 0  0(#(#0` (#(# ` (#` (#     0 ` 40CFR60SubpartVVStandardsofPerformanceforEquipmentLeaksofVOCintheSyntheticOrganicChemicalsManufacturingIndustry ` (#` (# Л  0   ` (1)0 (#(#Cytecshallcomplywiththepumpsinlightliquidserviceprovisionsspecified )#- in60.4822;  (# (#     0 ` (2)0 ` (#` (#Cytecshallcomplywiththecompressorprovisionsspecifiedin60.4823;D+t%/ (# (# 0     ` (3)0 (#(#Cytecshallcomplywiththepressurereliefdeviceingas/vaporservice ,@&0  provisionsspecifiedin60.4824;, '1 (# (#   0   ` (4)0 (#(#Cytecshallcomplywiththesamplingconnectionsystemprovisionsspecified   in60.4825;  (# (#     0 ` (5)0 ` (#` (#Cytecshallcomplywiththeopenendedvalvesorlinesprovisionsspecified h in60.4826;  (# (# 0     ` (6)0 (#(#Cytecshallcomplywiththevalvesingas/vaporserviceinlightliquidservice  0 provisionsspecifiedin60.4827;  (# (#   0   ` (7)0 (#(#Cytecshallcomplywiththepumpsandvalvesinheavyliquidservice,pres   surereliefdevicesinlightliquidorheavyliquidservice,andflangesandotherconnectorsprovisionsspecifiedin60.4828;  (# (#     0 ` (8)0 ` (#` (#Cytecshallcomplywiththedelayofrepairprovisionsspecifiedin60.4829; ,  (# (# 0     ` (9)0 (#(#Cytecshallcomplywiththeclosedventsystemandcontroldeviceprovisions    specifiedin60.48210;  (# (#   0   ` (10)0 (#(#Cytecshallcomplywiththetestmethodsandproceduresprovisionsspecified `  in60.485;  (# (#     0 ` (11)0 ` (#` (#Cytecshallcomplywiththereportingandrecordkeepingprovisionsspecified (  in60.486and60.487;  (# (# 0  0(#(#ShouldCytecseektousethealternativestandardsforvalves:allowablepercentageofvalvesleakingprovisionsspecifiedin60.4831,thealternativestandardsforvalves:skipperiodleakdetectionandrepairprovisionsspecifiedin60.4832,ortheequivalenceofmeansofemissionlimitationprovisionsspecifiedin60.484,theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(# 0    (D)0` (#(#40CFR60SubpartDDDStandardsofPerformanceforVolatileOrganicCompound   EmissionsfromthePolymerManufacturingIndustry ` (#` (# 0  0(#(#ShouldCytecbecomesubjecttoSubpartDDD,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR60.560,Cytecshalltakethefollowingcomplianceactions: (#(# М  0  0` (#(#0 ` (#` (#  (# (# 0  0(#(#0` (#(#40CFR60SubpartDDDStandardsofPerformanceforVolatileOrganicCompoundEmissions ` (#` (# 0  0(#(# ` (1)0 (#(#Cytecshallcomplywiththeprocessemissionsprovisionsspecifiedin P  60.5621;  (# (#   0   ` (2)0 (#(#CytecshallcomplywiththeequipmentleaksofVOCprovisionsspecifiedin  " 60.5622;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththemonitoringrequirementsprovisionsspecifiedin "$ 60.563;  (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththetestmethodsandproceduresprovisionsspecified $H& in60.564;  (# (#   0   ` (5)0 (#(#Cytecshallcomplywiththereportingandrecordkeepingprovisionsspecified %( in60.565;  (# (# 0  0(#(#(E)0` (#(#40CFR60SubpartNNNStandardsofPerformanceforVolatileOrganicCompound (D"+ EmissionsfromSyntheticOrganicChemicalManufacturingIndustryDistillationOperations ` (#` (# 0  0(#(#ShouldCytecbecomesubjecttoSubpartNNN,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR60.660,Cytecshalltakethefollowingcomplianceactions: (#(# М0  0(#(#0` (#(#40CFR60SubpartAGeneralProvisions ` (#` (#  -'2 0  0(#(#0` (#(#(1)0 ` (#` (#Cytecshallcomplywiththenotificationprovisionsspecifiedin60.7(a)(1)  through(4);  (# (# 0  0(#(#0` (#(#(2)0 ` (#` (#Cytecshallcomplywiththestandardsandmaintenancerequirements h specifiedin60.11(d).  (# (# 0  0(#(#0` (#(#40CFR60SubpartNNNStandardsofPerformanceforVolatileOrganicCompoundEmissionsfromSyntheticOrganicChemicalManufacturingIndustryDistillationOperations ` (#` (# Л0     ` (1)0 (#(#Cytecshallcomplywiththeemissionstandardprovisionsspecifiedin  ,  М60.662;  (# (#   0   ` (2)0 (#(#Cytecshallcomplywiththemonitoringofemissionsandoperations   provisionsspecifiedin60.663;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththetestmethodsandproceduresprovisionsspecified ,\  in60.664;  (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththereportingandrecordkeepingprovisionsspecified   in60.665;  (# (# 0  0(#(#ShouldCytecseektousetheoptionalemissionstandardprovisionsspecifiedin60.662(b)or(c),theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(# 0    (F)0` (#(#40CFR60SubpartRRRStandardsofPerformanceforVolatileOrganicCompound X EmissionsfromSyntheticOrganicChemicalManufacturingIndustryReactorϜProcesses ` (#` (# 0  0(#(#ShouldCytecbecomesubjecttoSubpartRRR,asdefinedbytheapplicabilitycriteriaspecifiedin40CFR60.700,Cytecshalltakethefollowingcomplianceactions: (#(# Л̜0  0(#(#0` (#(#40CFR60SubpartAGeneralProvisions ` (#` (# 0  0(#(#0` (#(#(1)0 ` (#` (#Cytecshallcomplywiththenotificationprovisionsspecifiedin60.7(a)(1)  through(4);  (# (# 0  0(#(#0` (#(#(2)0 ` (#` (#Cytecshallcomplywiththestandardsandmaintenancerequirements  L! specifiedin60.11(d).  (# (# 0  0(#(#0` (#(#40CFR60SubpartRRRStandardsofPerformanceforVolatileOrganicCompoundEmissionsfromSyntheticOrganicChemicalManufacturingIndustryReactorProcesses ` (#` (# Л0  0(#(# (#(# 0     ` (1)0 (#(#Cytecshallcomplywiththeemissionstandardprovisionsspecifiedin %( М60.702;  (# (#   0   ` (2)0 (#(#Cytecshallcomplywiththemonitoringofemissionsandoperations H'x!* provisionsspecifiedin60.703;  (# (#     0 ` (3)0 ` (#` (#Cytecshallcomplywiththetestmethodsandproceduresprovisionsspecified (#, in60.704;  (# (# 0     ` (4)0 (#(#Cytecshallcomplywiththereportingandrecordkeepingprovisionsspecified x*$. in60.705;  (# (#   ,@&0 0  0(#(#ShouldCytecseektousetheoptionalemissionstandardprovisionsspecifiedin60.702(b)or(c),theresultingrequirementswillbeincorporatedintothispermitusingthesignificantmodificationorpermitrenewalprocedures. (#(#  0    (G)0` (#(#40CFR60SubpartYYYStandardsofPerformanceforVolatileOrganicCompound  0 EmissionsfromSyntheticOrganicChemicalManufacturingIndustryWastewater  ` (#` (#  0  0(#(#ShouldCytecbecomesubjecttoSubpartYYY,asdefinedbytheapplicabilitycriteria p  specifiedin40CFR60.770,Cytecshalltakethefollowingcomplianceactions: (#(# 0     ` 40CFR60SubpartAGeneralProvisions (#(# 0  0(#(#0` (#(#(1)0 ` (#` (#Cytecshallcomplywiththenotificationprovisionsspecifiedin60.7(a)(1) l  through(4);  (# (# 0  0(#(#0` (#(#(2)0 ` (#` (#Cytecshallcomplywiththestandardsandmaintenancerequirements 4  specifiedin60.11(d).  (# (# 0  0(#(#40CFR60SubpartYYYStandardsofPerformanceforVolatileOrganicCompoundEmissionsfromSyntheticOrganicChemicalManufacturingIndustryWastewater (#(# 0  0(#(#0` (#(#(1)0 ` (#` (#Cytecshallcomplywiththegeneralstandardprovisionsspecifiedin60.773; (# (# 0     ` (2)0 (#(#Cytecshallcomplywiththetankprovisionsspecifiedin60.774; (# (# 0     ` (3)0 (#(#Cytecshallcomplywiththesurfaceimpoundmentsprovisionsspecifiedin d 60.775;  (# (# 0     ` (4)0 (#(#Cytecshallcomplycontainersprovisionsspecifiedin60.776;, (# (# 0     ` (5)0 (#(#Cytecshallcomplywiththeindividualdrainsprovisionsspecifiedin60.777; (# (#   0   ` (6)0 (#(#Cytecshallcomplywiththeoilwaterseparatorsprovisionsspecifiedin  60.778;  (# (#   0   ` (7)0 (#(#Cytecshallcomplywiththetreatmentprocessesprovisionsspecifiedin ,\ 60.779;  (# (#   0   ` (8)0 (#(#Cytecshallcomplywiththecontroldevicesprovisionsspecifiedin60.780; (# (#   0   ` (9)0 (#(#Cytecshallcomplywiththeinspectionandmonitoringofoperations  provisionsspecifiedin60.781;  (# (#   0   ` (10)0 (#(#Cytecshallcomplywiththetestingmethodsandprocedurestodetermine ( X! applicabilityprovisionsspecifiedin60.782;  (# (# 0     ` (11)0 (#(#Cytecshallcomplywiththetestingmethodsandprocedurestodetermine !# complianceprovisionsspecifiedin60.783;  (# (# 0     ` (12)0 (#(#Cytecshallcomplywiththereportingprovisionsspecifiedin60.784;X#% (# (#   0   ` (13)0 (#(#Cytecshallcomplywiththerecordkeepingprovisionsspecifiedin60.785;$$T& (# (#     0 ` (14)0 ` (#` (#Cytecshallcomplywiththeleakinspectionprovisionsspecifiedin60.786;$ ' (# (# 0  0(#(# (#(#  V.VOCRACTREQUIREMENTS  T'!* (a)  Purpose ((#, ThepurposeofthissectionistodescribetheVOCRACTrequirementsCytecissubjectto,andtoprovideameansofusingemissionsaveragingasanalternativemethodofcompliance.(b)  Definitions ,$'1  -'2 Forthepurposesofthissectionofthepermitthefollowingdefinitionsshallbeused. AnnualmassemissionstotalmeansthesumofallVOCemissions,evaluatedbeforecontrol,fromavent.AnnualmassemissionsmaybecalculatedfromanindividualprocessventorgroupsofprocessventsbyusingemissionestimationequationscontainedintheBatchProcessesACTandthenmultiplyingbytheexpecteddurationandfrequencyoftheemissionorgroupsofemissionsoverthecourseofayear.Forprocessesthathavebeenpermitted,theannualmassemissionstotalshouldbebasedonthepermittedlevels. AverageflowratemeansthegaseousexhaustflowrateaveragedovertheamountoftimethatVOCsareemitted.Fortheevaluationofaverageflowratefromanaggregateofsources,theaverageflowrateisthetimeweightedaverageoftheaverageflowratesevaluated. Batchmeansadiscontinuousprocessinvolvingthebulkmovementofmaterialthroughsequentialmanufacturingsteps. Emissionsaveragingplanmeansaplanapprovedinapermitmodificationthatincludesalloftheinformationrequiredbytheemissionsaveragingprovisionscontainedinthissection. EmissionlimitconsumingreferstoasourcethatispartofanemissionsaveragingplanthatemitsVOCatarategreaterthantheVOCemissionrateassociatedwithitsapplicableRACTrequirement.̜ Historicalactualaveragemeanstheactualaverageforthefiveyearperiodimmediatelyprecedingsubmissionoftheemissionsaveragingplan. Processmeansanyequipmentwithinacontiguousareathatareconnectedtogetherduringthecourseofayear,whereconnectedisdefinedasalinkbetweenequipment,whetheritisphysical,suchasapipe,orwhetheritisnextinaseriesofstepsinwhichmaterialistransferredfromoneunitoperationtoanother. Ventmeansapointofemissionfromaunitoperation.̜(c)  VOCRACTOrder P  ̜CytecwillcontinuetocomplywiththerequirementsofStateOrderNo.8012(attached),withtheexceptionoftheemissionlimitsforthebatchprocessventswhicharenotrequiredbytheordertoachieve85percentcontrol.TheseemissionlimitsaresupersededwithbytherequirementsspecifiedinsubsectionIV(d)effectivewiththeissuanceofthispermit.Thefollowingventsarerequiredtoachieve85percentcontrolpursuanttoStateOrderNo.8012:* "ddXdd dd dd dd dd dd "(#(#,fdd , dd +   %( EMISSIONSOURCEID  &D ) DESCRIPTION &D *  01PS09  t'!+ B-1#1CdScrubberVent  t'!, 01PS13  (#- B-1#3CdScrubberVent  (#. 05PS013  4*d$/ B-05/TR.102Reactor/Surge  4*d$0 05PS016  +%1 B-05/TR.120-13Condenser  +%2 05PS025  ,$'3 B-05/TR.120H20Scrubber  ,$'4 05PS054  d B-05/TR.150BlendTank  d 06PS021   B-06/TR.65/68TK71Cond.   06PS046  T $ B-06/TR.65/68K-65Cond.  T $ 06PS066    B-06/TR.103Condensers    06PS072     B-06/TR.104Condensers     06PS117B  tD  B-06/TR.65/68K-68Condensers  tD  06PS143    B-06/TR.106Condensers   06PS144  4  B-06/TR.107Condensers  4  06PS158  d  B-06/TR.114-8Scrubber  d  06PS160    B-06/TR.63/64Scrubber    06PS161  T$ B-06/TR.104-34Venturi  T$ 10PS081   B-10CarbonAdsorption   (d)  ControlofBatchProcessEmissionsunits |L   (i)0  SubjectEquipment(#(# 0  WiththeexceptionofthebatchprocessventsrequiredtobecontrolledbyStateOrderNo.8012,allbatchprocessventswillbecontrolledaccordingtothecriteriaspecifiedintheBatchϜProcessesACTinformationdocument.TheBatchProcessesACTspecifiescontrolofVOCemissionsfrombatchprocessventsintheorganicchemicalsindustry. (#(# 0  ThefollowingemissionsunitsincludebatchprocessventsasdefinedbytheBatchProcessesACT: (#(# *fa"bddfdd dd "(#(#f,dd , dd +    "% EMISSIONSUNIT  p"@& PROCESS p"@'   C03 #( Blending  #) C02  0%* BreakerPlateOven-Polymer  0%+ C06 !&`, !CYProductsDecantSystem !&`- !A04 !' . !DayFilters4,5,6,7 !' / !A04 !P) "0 !DayFilters8,9,10 !P) "1 !C07 !*#2 !DyePreparationSystem !*#3 !A04 !,$4 !ERPs !,$5 !A04 !p-@&6 !FumeFilters1,2,3 !p-@&7 !C05 !d !GraftingRubberSystem !d !A04 ! !KathabarRegenVent ! !R13 !T $ !Kettle61/62System !T $ !R14 !  !Kettle63/64System !  !R11 !   !MARS !   !R04 !tD  !MFRS !tD  !A03 !  !No.1Mixer/DryerSystem ! !A03 !4  !No.3Mixer/DryerSystem !4  !C10 !d  !PilotPlant !d  !C08 !  !PostColorOperations !  !C02 !T$ !ProcessCombustion !T$ !C08 ! !QCLab ! !C08 ! !QualityControl ! !C03 !tD !RE-100System !tD !C04 ! !RE-300System ! !C04 !4 !RE-400System !4  !C04 !d! !RE-500System !d" !R03 !# !Reactor101System !$ !R03 !T $% !Reactor102System !T $& !R05 !!' !Reactor103System !!( !R05 !#) !Reactor103/4System !#* !R05 !t$D+ !Reactor103/4/6/7System !t$D, !R05 !%- !Reactor104System !%. !R06 !4' / !Reactor104-34System !4' 0 !R05 !(d!1 !Reactor106System !(d!2 !R05 !)"3 !Reactor106/7System !)"4 !R05 !T+$$5 !Reactor107System !T+$$6 !R10 !,%7 !Reactor114-1System !,%8 !R08 !d ! Reactor150System !d !R04 ! !Reactor65/68System ! !R09 !T $ !ReactorK-66System !T $ !R03 !  !ResinsBldg.5 !  !R05 !   !ResinsBldg.6 !   !A02 !tD  !RK#3System !tD  !A02 !  !RK#4System ! !A04 !4  !Rolls !4  !A04 !d  !VacuumVents !d  !C01 !  !XTProductsDecantSystem  .   (ii)0  EquipmentRequiredtoControlVOCEmissions(#(#     (A) ` Applicability T$ 0  0(#(#TheBatchProcessesACTrecommendsreductionofVOCemissionsby90percentforindividualvents,orforventstreamsinaggregate,withinabatchprocess,havinganactualaverageflowratebelowthemaximumcosteffectiveflowrate(FR)ascalculatedaccordingtothefollowingformulas: (#(#   0  FR ` = 0.07(AE)1,821  (vaporpressurev75mmHg)(#(#      ` = 0.031(AE)494  (75mmHguvaporpressureu150mmHg)       ` = 0.013(AE)301  (vaporpressurex150mmHg) P      where: FR=themaximumflowrateatwhichcontroliscosteffective(scfm)  "      `  AE=annualmassemissionstotal(lb/yr)0  0(#(#Thefollowingemissionsunitshavebeendeterminedtocontainbatchprocessventsthat,inaggregate,meetthecosteffectivenesscriteriaspecifiedbytheBatchProcessesACTϜandshallachieve90percentcontrol: (#(#   0  [Thelistofsubjectsourceswillbedevelopedandmaintainedbasedonrecordsofemission %|) rateandflowratedata]&P*(#(#   (iii)0  Compliance ( ,(#(# 0  Cytecshallcomplywiththerequirementsofthissectionassoonasreasonablypractical,andinnoeventshallCytecattaincomplianceoveraperiodlongerthanoneyearunlessotherwiseapprovedbyDEP. (#(#   (iv)0  Monitoring,%2(#(#  -&3 0  Anycontroldevicerequiredtoachieve90percentcontrolshallbemonitoredconsistentwiththemethodsdescribedinthemonitoringsectionofthispermit. (#(#   (v)0  Recordkeeping4d(#(# 0  Cytecshallkeeprecordsforeachbatchprocessventforaminimumoffiveyears.Therecordsshallcomplywiththerecordkeepingsectionofthispermit. (#(# М(e)  EmissionsAveragingProvisions 0 `   (i)  Purpose    0  ThepurposeofthissubsectionistoestablishtherequirementsforusingemissionsaveragingϜtomeettheRACTlevelofreductionrequirementsforagroupofemissionsourcesatCytec.InlieuoftherequirementsforindividualVOCemissionsourcesdescribedinsubsectionsIV(c)andIV(d),Cytecmayachievethroughemissionsaveraginganequivalentlevelofemissionreductionforanygroupofemissionsources,whetherornottheyarewithinthesameCTGcategory,providedthattheconditionsdescribedinIV(e)aremet. (#(#   (ii)  RACTEquivalentEmissionLimitation $     (A)0 ` IntraCTGCategoryAveragingforBatchOperations` (#` (# 0  0(#(#TheallowableVOCemissionsrequiredbyRACTforagroupofbatchprocessemissionϜsourcesincludedinanintraCTGcategoryemissionsaveragingplanshallbeequaltotheϜsumoftheallowableemissionsoftheindividualsources.Theallowableemissionsoftheindividualsourcesshallbecalculatedbasedonthelesserofthefollowing: (#(# 0     ` (1)0 (#(#theemissionraterequiredbyRACTor; P (# (#   0   ` (2)0 (#(#thehistoricalactualaverageemissionrate. (# (# 0  0(#(#TheRACTequivalentemissions,EAllowable,shallbeamassofVOCemissions,calculated  foreachaveragingperiodas: (#(#   0   `    nz "(#(# 0    EAllowable =   &(&&&  s & &(S# W   sFC#  s   WԀS# &(&  seC##&&& &(C#Ԁ(ERBaseline,i,j󛀀xProductionActual,i,j)l!#(#(#      `    i=1j=1 "$ 0    where:0 (#(#n=0 (# (#0h(#(#0h(#h(#thenumberofemissionsourcesincludedinthe #,& averagingplan (#(#      ` 0 z=0 (# (#0h(#(#0h(#h(#thenumberofproductsmanufacturedbyemission %( Мsourcei (#(#      ` 0 ERBaseline,i,j󛀜=0h (# (#0h(#h(#thehistoricalactualaverageemissionrateorthe ,'\!* emissionraterequiredbyRACT,inunitsoflbϜVOC/batch,whicheverislower,forthemanufactureofproductjbysourcei (#(# М0  0(#(#ProductionActual,i,j=0(#(#theactualnumberofbatchesofproductjmanufacturedinsourcei \*$. duringtheaveragingperiod (#(# 0  0(#(#TheaveragingperiodoftheRACTequivalentemissionlimitationshallbeconsistentwiththeunderlyingRACTrequirement,butinnocaselongerthan30days.-'2(#(# Ї  0  Theactualemissions,EActual,oftheemissionsourcesincludedintheaveragingplan,shall  becalculatedforeachaveragingperiodas: (#(# ̛  0   `    nz4d(#(# 0    EActual =   &(&&&  s & &(S# W   sK#  s   WԀS# &(&  s8K##&&& &(|K#Ԁ(ERActual,i,j󛀀xProductionActual,i,j)(#(#      `    i=1j=1  (     where: n=0  0h(#(#0h(#h(#thenumberofemissionsourcesincludedinthe H x averagingplan (#(#      ` 0 z=0 (# (#0h(#(#0h(#h(#thenumberofproductsmanufacturedbytheemission    sourcesincludedintheaveragingplan (#(#      ` 0 ERActual,i,j󛀜=0h (# (#0h(#h(#theactualemissionrate,inunitsoflbVOC/batch,for x  themanufactureofproductjbysourcei,duringtheaveragingperiod (#(#      `  ProductionActual,i,j=0  theactualnumberofbatchesofproductj   manufacturedinsourceiduringtheaveragingperiod (#(# 0  0(#(#Theactualemissions,EActual,shallbemaintainedbelowtheallowableemissions,EAllowable, @p  Мforeachaveragingperiodduringthelifeoftheemissionsaveragingplan. (#(# 0  0(#(#(B)0` (#(#InterCTGCategoryAveraging` (#` (# 0  0(#(#TheallowableVOCemissionsperaveragingperiodrequiredbyRACTforagroupofbatchprocessemissionsourcesincludedinaninterCTGcategoryemissionsaveragingplanshallbeequaltothesumoftheemissionsoftheindividualsources.Theallowableemissionsoftheindividualemissionsourcesshallbecalculatedbasedonthelesserofthefollowing: (#(# 0     ` (1)0 (#(#theemissionraterequiredbyRACTor;4 (# (#   0   ` (2)0 (#(#thehistoricalactualaverageemissionrate. (# (# 0  0(#(#TheRACTequivalentemissions,EAllowable,shallbeamassofVOCemissions,calculated h Мforeachaveragingperiodas: (#(# М    EAllowable =  EAllowable,Batch+EAllowable,VOL+EAllowable,WWTP  "     where: EAllowable,Batch h =0  theRACTequivalentallowableemissionsassociated d"$ withthebatchprocessemissionsourcesincludedintheplan (#(# 0  0(#(#0` (#(#0 ` (#` (#EAllowable,VOL h =0 (# (#theRACTequivalentallowableemissionsassociated $' withthevolatileorganicliquidstoragetanksincludedintheplan (#(# 0  0(#(#0` (#(#0 ` (#` (#EAllowable,WWTP h =0 (# (#theRACTequivalentallowableemissionsassociated ,'\!* withthewastewatertreatmentplant,ifincludedintheplan (#(# Л  0   `    nz\*$.(#(# 0    EAllowable,Batch =   &(&&&  s & &(S# W   sY#  s   WԀS# &(&  sY##&&& &(AZ#Ԁ(ERBaseline,i,j󛀀xProductionActual,i,j)*%/(#(#      `    i=1j=1  ,P&0   ,&1 0    where:0 (#(#n=0 (# (#0h(#(#0h(#h(#thenumberofbatchprocessemissionsources   includedintheaveragingplan (#(#      ` 0 z=0 (# (#0h(#(#0h(#h(#thenumberofproductsmanufacturedbybatch h processemissionsourcei (#(#      ` 0 ERBaseline,i,j󛀜=0h (# (#0h(#h(#thehistoricalactualaverageemissionratefromthe  0 batchprocessemissionsourcesortheemissionraterequiredbyRACT,whicheverislower,inunitsoflbVOC/batch,forthemanufactureofproductjbysourceϜi (#(#      ` 0 ProductionActual,i,j=0 (# (#theactualnumberofbatchesofproductj  ,  manufacturedinsourceiduringtheaveragingperiod (#(#   0   `    n h      p   LJ&Ԁ#&&LB`#Ԁn` (#(# 0    EAllowable,VOL =   &(&&&  s & &(S# W   s`#  s   WԀ# &(&  sa##&&& &(]a#(ERBaseline,Working,ixProductionActual,i)+t&&Ԁ#&&ta# &(&&&  s & &(S# W   s@b##&&  W_b#ԀEBaseline,Breathing,i (#(#      `    i=1 h      p   i=1 $T  0    where:0 (#(#n=0 (# (#0h(#(#0h(#h(#thenumberofvolatileorganicliquidstoragetanks t  includedintheaveragingplan (#(#      ` 0 ERBaseline,Working,i=0 (# (#thehistoricalactualaverageemissionrateorthe  < emissionraterequiredbyRACT,whicheverislower,inunitsoflbVOC/galthroughput,duetoworkinglossfromstoragetanki (#(#      ` 0 ProductionActual,i=0 (# (#theactualthroughput,ingal,intostoragetanki, <l duringtheaveragingperiod (#(# 0  0(#(#0` (#(#0 ` (#` (#EBaseline,Breathing,i=0 (# (#thehistoricalactualaverageemissionsorthe  emissionsrequiredbyRACT,whicheverislower,inunitsoflbVOC,duetobreathinglossfromstoragetankiovertheaveragingperiod (#(# 0    EAllowable,WWTP =  ERBaselinexProductionActual(#(#     where: ERBaseline=0 h 0h(#h(#thehistoricalactualaverageemissionratefromthe h wastewatertreatmentplantortheemissionraterequiredbyRACT,whicheverislower,inunitsoflb/galofwastewatertreated (#(#      `  ProductionActual=0  theactualvolumeofwastewatertreatedbythe !# wastewatertreatmentplant,inunitsofgal/month,duringtheaveragingperiod (#(# 0  0(#(#TheaveragingperiodoftheRACTequivalentemissionlimitationshallbeconsistentwiththeunderlyingRACTrequirement,butinnocaselongerthan30days. (#(#   0  Theactualemissions,EActual,oftheemissionsourcesincludedintheaveragingplan,shall ,'\!* becalculatedforeachaveragingperiodas: (#(#     EActual0 =  EActual,Batch+EActual,VOL+EActual,WWTP)#- (# (#     where: EActual,Batch h =0  theactualemissionsfromthebatchprocessemission (+X%/ sourcesincludedintheplan (#(# 0  0(#(#0` (#(#0 ` (#` (#EActual,VOL h =0 (# (#theactualemissionsfromthevolatileorganicliquid ,&1 storagetanksincludedintheplan-'2(#(# 0  0(#(#0` (#(#0 ` (#` (#EActual,WWTP h =0 (# (#theactualemissionsfromthewastewatertreatment  plant,ifincludedintheplan (#(# Л  0   `    nz4d(#(# 0    EActual,Batch =   &(&&&  s & &(S# W   sp#  s   WԀS# &(&  sp##&&& &(p#Ԁ(ERActual,i,j󛀀xProductionActual,i,j)(#(#      `    i=1j=1  (     where:0 n=0 (# (#0h(#(#thenumberofbatchprocessemissionsourcesincludedinthe H x averagingplan h(#h(#      ` 0 z=0 (# (#0h(#(#thenumberofproductsmanufacturedbybatchprocess    emissionsourcei h(#h(#      ` 0 ERActual,i,j=0h (# (#theactualemissionrate,inunitsoflbVOC/batch,forthe x  manufactureofproductjbysourcei,duringtheaveragingperiod h(#h(#      ` ProductionActual,i,j=0 h theactualnumberofbatchesofproductjmanufacturedin   sourceiduringtheaveragingperiod h(#h(#   0   `    n h      p n@p (#(# 0    EActual,VOL =   &(&&&  s & &(S# W   suv##&&  Wߔv#(ERActual,ixProductionActual,i)++&&Ԁ#&&++w# &(&&&  s & &(S# W   snw##&&  Wߍw#ԀEActual,Breathing,i (#(#      `    i=1 h      p i=1 4 0    where:0 (#(#n=0 (# (#0h(#(#0h(#h(#thenumberofvolatileorganicliquidstoragetanks T includedintheaveragingplan (#(#      ` 0 ERActual,i=0h (# (#0h(#h(#theactualemissionratefromstoragetanki,inunits  oflbVOC/galthroughput,duetoworkinglossfromstoragetanki,duringtheaveragingperiod (#(#      ` 0 ProductionActual,i=0 (# (#theactualthroughput,ingal,intostoragetanki, P duringtheaveragingperiod (#(# 0  0(#(#0` (#(#0 ` (#` (#EActual,Breathing,i=0h (# (#theactualemissionsduetobreathinglossfromstoragetank  iduringtheaveragingperiod h(#h(# 0    EActual,WWTP =  ERActualxProductionActualL|(#(#     where: ERActual=0 h 0h(#h(#theactualemissionratefromthewastewater ! treatmentplant,inunitsoflb/galofwastewatertreated,duringtheaveragingperiod (#(#      `  ProductionActual=0  theactualvolumeofwastewatertreatedbythe H"x$ wastewatertreatmentplant,inunitsofgal/month,duringtheaveragingperiod (#(# Л0  0(#(#Theactualemissions,EActual,shallbemaintainedbelowtheallowableemissions,EAllowable, x%( foreachaveragingperiodduringthelifeoftheemissionsaveragingplan. (#(#   (iii)0  RegulatedHazardousAirPollutants[STATEONLY]' "+(#(#     (A)0 ` AdditionalRequirementsforIntraCTGCategoryTrading|)#-` (#` (# 0  0(#(#IfaregulatedVOChazardousairpollutantisemittedfromanyoftheemissionsourcesincludedintheemissionsaveragingplan,CytecshallthendemonstratecompliancewithRCSA22a17429,Tables291,2,and3foreachemissionsourceincludedintheplan. (#(#  x-'2     (B)0 ` AdditionalRequirementsforInterCTGCategoryTrading` (#` (# 0  0(#(#IfaregulatedVOChazardousairpollutantisemittedfromanyoftheemissionsourcesincludedintheemissionsaveragingplan,thenCytecshall: (#(#      ` (1)0 Quantifyhazardousairpollutantemissionratesconsistentwiththeemissions   quantificationsectionofthispermit,includingperformingemissionstestingasnecessary;  (# (#     0 ` (2)0 ` (#` (#DemonstratecompliancewithRCSA22a17429,Tables291,2,and3; ,  (# (#      ` (3)0 Performalimitedassessmentindicatingtheproposedemissionsaveraging   willnotcreateanunacceptablerisktohumanhealth.  (# (#   0  [NotethatDEPhasnotyetformalizeditsinterCTGcategorytradingpolicy]( (#(#   (iv)0  PlanImplementation (#(#     (A) ` IncorporationIntoPermit 0` 0  0(#(#Priortoinitiation,anemissionsaveragingplanwillbeincorporatedintothispermitusingtheminorpermitmodificationprocedure. (#(#   0  (B)0` (#(#PlanModifications,\` (#` (# 0  0(#(#Anyproposedchangestoanemissionsaveragingplanwillbeincorporatedintothispermitusingtheminorpermitmodificationprocedurepriortoimplementation. (#(# М̛  (v)0  Monitoring(X(#(# 0  0(#(#Anyemissionsourcescontainedinanemissionsaveragingplanregisteredunderthissubsectionshallbemonitoredconsistentwiththemethodsdescribedinthemonitoringsectionofthispermit. (#(# М̛̜ VI.APPROVEDCONNECTICUTSIPREQUIREMENTS  !# (a)ApprovedSIPRequirements̜CytecissubjecttothefollowingEPAapprovedCTSIPrequirements:  (i)0  RCSA22a1743(c)Standardsforgrantingapermittoconstruct& )(#(#   Cyteccurrentlyhasconstructionpermitsforthefollowingequipment:*fi"jd/ddd dd a"b(#(#f, dd ,dd ,dd ,( dd +   )#- SOURCEDESCRIPTION  $*T$. DEPPERMITNO.  * %0 DATE  $*T$1 REQUIREMENTS $*T$2  WWTPLimeSilo :0 P,&3  # H >W  I.PURPOSE   Thepurposeofthissectionistodescribethemonitoringmethodsthatwillbeemployedandthemonitoringdatathatwillberecordedtodemonstratecompliancewithapplicablerequirements.Monitoringofairpollutantemissionsfromcontroldevicesaswellasemissionsourcesisdescribed. II.MONITORINGMETHODS  @   (a)0  CategoriesofEmissionSources (#(# ThecategoriesofemissionsourcespresentatCytecaredescribedintheemissionsquantificationsection.(b)EmissionSourceMonitoringMethods  (i)0  Foranyemissionsourcesubjecttoanapplicablerequirementwhichdefinesthemonitoring x0 requirements,Cytecshallperformmonitoringconsistentwiththeapplicablerequirement.Ifmorethanoneapplicablerequirementdefinesthemonitoringrequirementsforanemissionsource,Cytecshallperformthatmonitoringwhichismostprecise,accurate,andcontinuous,andwhichcanbereliedupontodemonstratewhetherCyteccomplieswitheachapplicablerequirementasidentifiedintheemissionsunitssectionofthispermit.Ifanapplicablerequirementspecifiesmonitoringnotsufficienttoyielddatathatcanbereliedupontodemonstratecompliance,thenmonitoringwillbeperformedconsistentwithII(b)(ii). (#(#   (ii)0  Foranyemissionsourcesubjecttoanapplicablerequirementwhichdoesnotspecify \ emissionsmonitoringsufficienttoyielddatathatcanbereliedupontodeterminecompliance,orforwhichanairpollutantemissionrateisrelieduponindemonstratingthatarequirementisnotapplicable,thefollowingtableliststheemissionsmonitoringparametersforeachclassofpollutantemittedfromasourcecategory. (#(# *wx"yd d( dd ( dd ( dd n"o(#(#w,dd ,Fdd ,rdd ,Fdd ,dd +   l$# МSOURCECATEGORY  $ POLLUTANTTYPE   T& PARAMETER  ' МSENSITIVITY  ( MONITORINGFREQUENCY  T*  BatchorSemiContinuousProcesses  ", Gaseous  !- Numberandtypeofbatchesprocessed  #L 0 1batch  !1 Monthly  !2  "$!3 "Liquid/solid  $!4 Numberandtypeofbatchesprocessed  &D#7 1batch  $!8 Monthly  $!9 Combustion  '$: All  '$; Typeandvolumeoffuelburned  (p%= М1cfor1gal  '$> Daily  '$? DirectContactCooling  *&@ All  *&A Watervolumetricflow  *'C 1gal  *&D Monthly  *&Eg EquipmentLeakFugitives  , 0 Gaseous  `d Durationofpressurized service    1hour  `d Monthly  `d Incineration  X \  All  X \  Massofsludgetreated  $ (  1ton  X \  Monthly  X \ Landfill    All    Visualinspection        Periodic    LiquidStorage * E9 *Gaseous/Vapor &E &Tankscontents,throughput   1gal   Monthly         Temperatureifheated    1F    Monthly    Remediation  <@  All  <@  Massofmaterialprocessed   " 1ton  <@ # Periodic  <@ $ WastewaterTreatment * 48&  *Gaseous &hl '  &Volumeofwastewatertreated  * 1gal  hl + Daily  hl ,   ,   , TOCconcentrationsofinfluentandeffluent  0 1ppmwor1mg/l  ,02 Daily ,04 Refertotheemissionsunitssectionandanynoticesattachedtothispermitfornewemissionsunitsforthespecificmonitoringmethodemployedforagivenemissionsource.(c)  CategoriesofControlEquipment 8 ThecategoriesofcontrolequipmentpresentatCytecaredescribedintheemissionsquantificationsection.(d)ControlEquipmentMonitoringMethodsAnycontrolequipmentthatisneededtomeetanemissionlimitthatispartofanapplicablerequirement,orwhichisrelieduponindemonstratingthatarequirementisnotapplicable,orwhichisregisteredundertheemissionsVreductionVVlimitationVsectionofthispermitshallbemonitoredinaccordancewiththissubsection.0  (i)0(#(#Foranycontroldevicesubjecttoanapplicablerequirementwhichdefinesthemonitoring ( D requirements,Cytecshallperformmonitoringconsistentwiththeapplicablerequirement.Ifmorethanoneapplicablerequirementdefinesthemonitoringrequirementsforacontroldevice,Cytecshallperformthatmonitoringwhichismostprecise,accurate,andcontinuousasidentifiedintheemissionsunitssectionofthispermit.Ifanapplicable requirementspecifiesmonitoringnotsufficienttoyielddatathatcanberelieduponto |,$I Мdeterminecompliance,thenmonitoringwillbeperformedconsistentwithII(d)(ii)andII(d)(iii). (#(#  0  (ii)0(#(#Foranycontroldevicesubjecttoanapplicablerequirementwhichdoesnotspecify 4d emissionsmonitoringsufficienttoyielddatathatcanbereliedupontodeterminecompliance,orforwhichanairpollutantemissionrateisrelieduponindemonstratingthatarequirementisnotapplicable,forwhichthecontrolefficiencywasdeterminedinaccordancewithsubsectionII(d)(ii)(A)oftheemissionsquantificationsectionofthispermit,ϜCytecshallmonitorthosevariablesusedtocalculatecontrolefficiencythatmostaffecttheemissionrateasidentifiedintheemissionsunitssectionofthispermit. (#(# 0  (iii)0(#(#Foranycontroldevicesubjecttoanapplicablerequirementwhichdoesnotspecify   emissionsmonitoringsufficienttoyielddatathatcanbereliedupontodeterminecompliance,orforwhichanairpollutantemissionrateisrelieduponindemonstratingthatarequirementisnotapplicable,forwhichtheemissionratewasestablishedthroughtestinginaccordancewithsubsectionsII(d)(ii)(B)orII(d)(ii)(C)oftheemissionsquantificationsectionofthispermit,Cytecshallmonitoreachofthefollowingparameters: (#(# *z"{d ddd Fdd rdd Fdd dd x"y(#(#,dd ,dd ,dd ,dd +   (X CONTROLDEVICE  X OPERATINGPARAMETER  X MEASUREMENT̜SENSITIVITY  X MEASUREMENTFREQUENCY "X   Baghouse "" "PressureDrop   М10percentofdesignpressuredrop   МRecordeddailyortripalarm "   Adsorber 3)'!"" 3DurationBetweenBedRegeneration  # М10percentofdesigncycletime  |& Periodic " '  %x'" %DurationBetweenBedReplacement  ) Months   * Periodic "  + МAdsorber 3)'8,"" 3TemperatureofInlet  8- М2F  8. МRecordedevery6minutesortripalarm  0   0 VolumetricFlowRate  4 d1 М100cfmor1percentofmaximumflowrate  !03 Recordedonceper4hours  !05 Condenser  `"6 CondenserExitTemperature  ,#\8 М2F  `"9 МRecordedonceperminuteortripalarm  ,#\; ElectrostaticPrecipitators &$&T > || &PowerSupply  $? 0.1kW  $@ МRecordedonceperminute " X%B  %T& B" %InletTemperature  & C М2F  & D МRecordedonceperminute  '!F ThermalDestructionUnits  )#H OperatingTemperature  )#J М2F  (#K МRecordedonceperminute  )#M  "+@%N "ExitOxygenConcentration  + &P 0.1percent  +@%Q МRecordedonceperminute  + &S Centrifugal Separators  , 0 ExhaustFlowRate  `d 100cfmor1percent  `d Monthly  `d ScrubbersOrganicVaporPollutants  $ ( ScrubbingLiquidFeedTemperature  X \  М2F     МRecordedonceperminuteortripalarm  X \  ScrubbersGaseousInorganicPollutants ' 'ScrubbingLiquidFeedpH 'PT '0.1pHunit '  'Continuouslyindicatedandtripalarm PT ScrubbersSolidPollutants    PressureDrop  HL  М10percentofdesignpressuredrop    Recordedonceperminuteortripalarm    0  ThevalueofeachparameterthatdemonstratescomplianceisspecifiedintheemissionsunitssectionofthispermitoronanotificationsubmittedpursuanttotheemissionsVreductionVVlimitationVsectionofthispermit. (#(# 0  (iv)0(#(#Intheeventofunexpectedequipmentfailureorplannedtemporarymaintenance,Cytec  " maymonitorthefollowingsurrogateparametersinlieuoftheparametersspecifiedinII(d)(iii): (#(# *|"}dddd dd dd dd z"{(#(#,dd ,4dd ,dd ,dd +   <@& CONTROLDEVICE  lp( OPERATINGPARAMETER  lp* MEASUREMENT̜SENSITIVITY  lp, MEASUREMENTFREQUENCY !""lp.  !Baghouse "/"" "VisualOpacity  0 М5percent  1 DailyMethod9observation  3 Adsorber  4 HydrocarbonConcentration  6 М5ppmv  7 МRecordedonceperϜday  9 ElectrostaticPrecipitators  !; VisualOpacity  $!(< М5percent  $!(= DailyMethod9observation  !? ThermalDestructionUnits  $ A HydrocarbonConcentration  $ C М5ppmv  P#TD МRecordedonceperϜday  $ F Condenser  |%G CondenserLiquidFeedTemperature  H&LI 1F  |%J МRecordedonceper6minutes  H&LL CentrifugalSeparators  t(x N VisualOpacity  'O М5percent  'P MonthlyMethod9observation  t(x R ScrubbersϜOrganicVaporPollutants  l+p#U ScrubbingLiquidSourceTemperature  *"W 1F  )!X МRecordedhourly  )!Y ScrubbersGaseousInorganic Pollutants '  'LiquidFeedRate '`d '10percentofdesignfeedrate ', 0 'Recordedhourly `d ScrubbersSolidPollutants  $ (  МLiquidFeedRate  X \  М10percentofdesignfeedrate  $ (  МRecordedhourly X \  0  ThevalueofeachparameterthatdemonstratescomplianceisspecifiedintheemissionsunitssectionofthispermitoronanotificationissuedpursuanttotheemissionsVreductVVlimitationVVionVsectionofthispermit.Incaseofunexpectedequipmentfailure,Cytecshallmakereasonableefforttorepairallaffectedequipmentassoonaspractical.InnocaseshallCyteccontinuetooperateequipmentwhichisrequiredtobemonitoredinaccordancewithII(d)(iii)whileusingsurrogateparametersformorethan15days,unlessotherwiseapprovedbyDEP.UponmonitoringsurrogateparametersinlieuoftheparametersspecifiedinII(d)(iii)CytecshallnotifyDEPassoonaspractical,butnotlaterthansevenbusinessdays. (#(# ̜(e)0  NewEmissionSourceCategories (#(# 0  (i)0(#(#Foranewemissionsourcesubjecttoanapplicablerequirementwhichdefinesthe  monitoringrequirements,Cytecshallperformmonitoringconsistentwiththeapplicablerequirement.Ifmorethanoneapplicablerequirementdefinesthemonitoringrequirementsforanemissionsource,Cytecshallperformthatmonitoringwhichismostprecise,accurate,andcontinuous,andwhichcanbereliedupontodemonstratewhetherCytecϜcomplieswithallapplicablerequirementsasidentifiedintheemissionsunitssectionofthisϜpermit.Ifanapplicablerequirementspecifiesmonitoringnotsufficienttoyielddatathatcanbereliedupontodeterminecompliance,thenmonitoringwillbeperformedconsistentwithII(e)(ii). (#(# 0  (ii)0(#(#Foranewemissionsourceorcontroldevice,subjecttoanapplicablerequirementwhich # doesnotspecifyemissionsmonitoringthatcanbereliedupontodeterminecompliance,orforwhichanairpollutantemissionrateisrelieduponindemonstratingthatarequirementisnotapplicable,emissionsshallbemonitoredusingmethodsprovidedforinII(b)or(d)whereapplicable. (#(# 0  (iii)0(#(#Ifthenewsourceorcontroldevicecannotberepresentedbyanyofthecategories p#t) containedinII(a)orII(c)ofthissection,theemissionsshallbemonitoredaccordingtothefollowinghierarchy: (#(#     (A)0 ` Ifdataisavailable,required,orwarrantedfromcontinuousmonitoringequipment &- installed,operated,andcertifiedinaccordancewithapermit,order,orregulationissuedoradministeredbytheCommissionerortheAdministrator,continuousmonitoringshallbeperformed; ` (#` (#     (B)0 ` Ifsuchcontinuousmonitoringdataisunavailablebutstacktestingdataisavailable, *"2 required,orwarranted,theemissionsrelatedparametersmonitoredduringthestacktestshallbemeasuredtomonitoremissions,providedsuchtestingwasconducted inaccordancewiththeprocedurescontainedin40CFR51AppendicesMandP,40 -%5 CFR60AppendicesAandF,40CFR61AppendicesBandC,or40CFR63AppendicesAandC,orapprovedbytheAdministrator;or ` (#` (#      (C)0 ` Ifsuchstacktestingisunavailable,buttherateofemissionswasdeterminedusing 4d datasuppliedbythemanufacturerofthesubjectemissionsunit,whichdatawasderivedfromEPAapprovedemissionstestingofsuchunitorsimilarunitperformedbythemanufacturer,theemissionsrelatedparametersmonitoredduringthestacktestshallbemeasuredtomonitoremissions;or ` (#` (#     (D)0 ` Ifsuchmanufacturersdataisunavailable,buttheemissionsratecanbecalculated  ,  usingdataderivedfromananalysisofpertinentmaterialbalancesconductedbyanindividualwithappropriateknowledgeofthesubjectprocesswheretheemissionsunitcanbeaccuratelymonitoredusingamaterialbalance,thenthemassofmaterialsinvolvedinthebalanceshallbemeasuredtomonitoremissions; ` (#` (#     (E)0 ` Ifdatafromsuchamaterialbalanceanalysisisunavailable,buttheemissionsrate   canbecalculatedusingdatafrom CompilationofAirPollutantEmissionFactors(AP42)publishedbyEPAwherethereisanemissionfactorappropriatefortheemissionsource,thenemissionsshallbemonitoredbymeasuringtheparametersincludedintheemissionfactor;or ` (#` (#     (F)0 ` Ifdatafromtheabovemethodsisunavailableorinappropriate,emissionsshallbe  monitoredinaccordancewithaproposalsubmittedbyCytecandapprovedbytheCommissionerinwriting. ` (#` (# 0  ThepermitshallberevisedtodefinethemonitoringrequiredforanynewemissionsourceϜcoveredundersectionII(e)(iii).MonitoringdefinedaccordingtoII(e)(iii)(A)throughII(e)(iii)(E)shallbeincorporatedpursuanttotheminorpermitmodificationprocedure.MonitoringdefinedaccordingtoII(e)(iii)(F)shallbeincorporatedpursuanttothesignificantpermitmodificationprocedure. (#(# (f)0  CategoriesofOperationalLimitations(#(# Thecategoriesofoperationallimitationsaredescribedintheemissionslimitationsection.(g)OperationalLimitationsMonitoringMethodsAnyoperationallimitationthatisneededtomeetanemissionlimitthatispartofanapplicablerequirement,orwhichisrelieduponindemonstratingthatarequirementisnotapplicable,orwhichisregisteredundertheoperationallimitationssectionofthispermitshallbemonitoredinaccordancewiththissubsection.0  (i)0(#(#Foranoperationallimitationsubjecttoanapplicablerequirementwhichdefinesthe H'x!* monitoringrequirements,Cytecshallperformmonitoringconsistentwiththeapplicablerequirement.Ifmorethanoneapplicablerequirementdefinesthemonitoringrequirementsforanoperationallimitation,Cytecshallperformthatmonitoringwhichismostprecise,accurate,andcontinuousasidentifiedintheemissionsunitssectionofthispermit.Ifanapplicablerequirementspecifiesmonitoringnotsufficienttoyielddatathatcanbereliedupontodeterminecompliance,thenmonitoringwillbeperformedconsistentwithII(d)(ii)andII(d)(iii). (#(#  -'2 0  (ii)0(#(#Foranoperationallimitationsubjecttoanapplicablerequirementwhichdoesnotspecify  emissionsmonitoringsufficienttoyielddatathatcanbereliedupontodeterminecompliance,orforwhichanairpollutantemissionrateisrelieduponindemonstratingthatarequirementisnotapplicable,thefollowingtableliststheemissionsmonitoringparametersfortheoperationallimitation: (#(# *K"Ld ddd 4dd dd dd |"}(#(#,dd ,dd ,dd ,dd +     OPERATIONALLIMITATION    MONITORINGMETHOD     MEASUREMENTSENSITIVITY     MEASUREMENTFREQUENCY $"   $HoursofOperation 3)' $" 3Meter  ( X Lesserof1houror1%ofrestriction   $ Continuous,asused " ( X  % " %LogSheet  T  Lesserof1houror1%ofrestriction   P  Periodic,asused " T  FuelorRawMaterialUse 3)'L| "G" 3Meter    1%ofrestriction    Continuous,asused "    %| " %LogSheet    1%ofrestriction    Periodic,asused "   ConcurrentUsage 3)'@p!"O" 3Meter  @p" Asneededtoshowcompliance   <$ Continuous,asused " @p%  %8%" %LogSheet  l& Asneededtoshowcompliance  8h( Periodic,asused l)  0  ThevalueofeachparameterthatdemonstratescomplianceisspecifiedintheemissionsunitssectionofthispermitoronanotificationsubmittedpursuanttotheemissionsVreductionVVlimitationVsectionofthispermit. (#(# (h)0  CategoriesofPollutionPreventionMeasures0`.(#(# ThecategoriesofpollutionpreventionmeasuresaredescribedintheemissionsVreductionVVlimitationVsection.(i)PollutionPreventionMonitoringMethodsAnypollutionpreventionmeasurethatisneededtomeetanemissionlimitthatispartofanapplicablerequirement,orwhichisrelieduponindemonstratingthatarequirementisnotapplicable,orwhichisregisteredunderthepollutionpreventionmeasuressectionofthispermitshallbemonitoredinaccordancewiththissubsection.0  (i)0(#(#Foranpollutionpreventionmeasuresubjecttoanapplicablerequirementwhichdefines $$9 themonitoringrequirements,Cytecshallperformmonitoringconsistentwiththeapplicablerequirement.Ifmorethanoneapplicablerequirementdefinesthemonitoringrequirementsforanpollutionpreventionmeasure,Cytecshallperformthatmonitoringwhichismostprecise,accurate,andcontinuousasidentifiedintheemissionsunitssectionofthispermit.Ifanapplicablerequirementspecifiesmonitoringnotsufficienttoyielddatathatcanbereliedupontodeterminecompliance,thenmonitoringwillbeperformedconsistentwithII(d)(ii)andII(d)(iii). (#(# 0  (ii)0(#(#Foranpollutionpreventionmeasuresubjecttoanapplicablerequirementwhichdoesnot  ,P&B specifyemissionsmonitoringsufficienttoyielddatathatcanbereliedupontodeterminecompliance,orforwhichanairpollutantemissionrateisrelieduponindemonstratingthat -'D arequirementisnotapplicable,thefollowingtableliststheemissionsmonitoringparametersforthepollutionpreventionmeasure: (#(#     (A)0 ` Operatingpracticesthatreduceairpollutiongeneration4d` (#` (#     (B)0 ` Rawmaterialsubstitutions 0` (#` (#     (C)0 ` Processandequipmentdesign ` (#` (# *`"hdddd dd dd dd K"L(#(#,dd ,dd ,dd ,dd +   0 ` POLLUTIONPREVENTIONMEASURE  ,\  MONITORINGMETHOD  `   MEASUREMENTSENSITIVITY  `  MEASUREMENTFREQUENCY "`    OperatingPractice " " "Logofoperatingmethod  X  Asneededtoshowcompliance  X  Periodic,asused "   RawMaterialSubstitution " " "Logofrawmaterialusedinprocess    Asneededtoshowcompliance    Periodic,asused    0  ThevalueofeachparameterthatdemonstratescomplianceisspecifiedintheemissionsunitssectionofthispermitoronanotificationsubmittedpursuanttotheemissionsVreductionVVlimitationVsectionofthispermit. (#(#   "  XeX&&  W CYTECTITLEVPERMIT  PREAPPROVEDMODIFICATIONS OSECTION #&&XXe# H [\   I.PURPOSE    ThissectiondescribestherequirementsforspecificsourcesandcategoriesofsourcesthatCytecϜmaycomplywithinlieuofobtainingaNSRpermitandTitleVpermitmodification.AnynewsourceormodificationcoveredunderthissectionmustnotbemajorasdefinedbyRCSA22a1741.̜ II.NSRGENERALPERMITS  t ,  ̜CytecisallowedtoconstructandoperateanyemissionsourceincompliancewithanewsourcereviewgeneralpermitheldbytheDEPCommissionerafterregisteringundersuchpermit.  III.FUELBURNINGSOURCES \  H  ̜Cytecisallowedtoconstructandoperateoneboilermeetingthefollowingoperationalparameters.  FuelType: `     h     NaturalGas <   Minimumstackheight(ft): h      p _____ P   Minimumdistancefromstacktopropertyline(ft): p 70    Maximumfuelconsumptionoverany    consecutive12monthperiod(mmft3):0   p _____l(#(#   Maximumgrossheatinput(MMBtu/hr):    99 8   Minimumexhaustgasflowrate(acfm):    _____ L   Designstackexittemperatureused  0  fordispersionmodelingpurposes(oF):   p _____(#(# ̜Ifconstructed,theboilershallbesubjecttothefollowingrequirements:(a)  40CFR60SubpartDcRequirements   TheboilershallbesubjecttotherequirementsofthisSubpart,however,theonlysectiontowhichtheboilerwillbesubjectis60.48c(Reportingandrecordkeepingrequirements).Cytecshallfulfilltherequirementsofboth60.48candthenotificationsectionofthispermit.(b)  MinorsourceBACTrequirement !& ABACTanalysiswasperformedforTSP,NOXandCO.Thefollowingaretheresultsofthat t#, ( analysis:  (i)0  TSPemissionlimit:0.0137lb/MMBtu.Technique:Goodcombustionpractices%"+(#(#   (ii)  NOXemissionlimit:0.043lb/MMBtu.Technique:FGR,LowNOXburner. p'($-   (iii)  COemissionlimit:0.035lb/MMBtu.Technique:Goodcombustionpractices. )%/ ̜[Note:theabovevaluesareunderreviewandmayberevisedafterfurtherevaluation] *X'1 (c)  Stacktestingrequirements @,(3 ̜CytecshallperformstacktestinginaccordancewiththemethodscitedinRCSA22a1745(b). -*5 Ї(d)  AmbientImpactAnalysis  AStationarySourceStackHeightGuidelineAnalysiswasperformedperRCSA22a1743.TheGoodEngineeringPractice(GEP)StackHeightwasdeterminedbythemethoddescribedin40CFR51.100(ii).Thestackheightshallbeaminimumof___feet.(e)  HAPEmissions[STATEONLY]   TheonlyHAPemittedbygasfiredboilersisformaldehyde.TheboilershallcomplywiththeRCSA22a17429MASCof______g/m3.  4     IV.VOLATILEORGANICLIQUIDSTORAGETANKS   h  CytecisallowedtoconstructandoperateanynumberofVOLstoragetanksasdescribedinthissectionsubjecttothefollowingprovisionsandthosesetforthinthePALsectionofthispermit.(a)  40CFR60SubpartKbRequirements p  Tanksequaltoorgreaterthan40m3(10,567gal)insizearesubjecttothisSubpartasdetailed 8 below.  (i)  60.112bStandardforvolatileorganiccompounds l   Tanksmeetingthefollowingcriteriaaresubjecttothissection:     ` *@"Ndddd dd dd dd `"h(#(#, dd , dd +    CAPACITY,m3(gal) '0" 'VAPORPRESSURE,kPa(psi) '0" '>151(39,890) '`" '>5.2(.75),<76.6(11.11) '`" '>75(19813),<151(39,890) '" '>27.6(4.00),<76.6(11.11)" "  "  !   Thesetanksshallinstalloneofthefollowingcontrolschemes:*fI"Odd dd dd @"N(#(#f,dd , dd +   h ID# '" 'CONTROLSCHEME F<"  ?1?F1 F<1, \"  ?1 ? FFixedroofwithinternalfloatingroof F<, \  @2@F2 F<1 "  @2 @ FExternalfloatingroof F<   @3@F3 F<1  "  @3 @ FClosedventsystemwithcontroldevice"    "  (ii)  60.113bTestingandprocedures      Tanksrequiringcontrolschemesshallbesubjecttothecitedparagraphsofthissection:*f?"Pdddd dd I"O(#(#f,dd , dd +     ID# 'Hx " 'APPLICABLEPARAGRAPH F<Hx "  ?1?F1 F<1 "  ?1 ? F60.113b(a) F< "  @2@F2 F<18"  @2 @ F60.113b(b) F<8"  @3@F3 F<1h"  @3 @ F60.113b(c)"h"  "  (iii)  60.115bReportingandrecordkeepingrequirements 0`   Tanksrequiringcontrolschemesshallbesubjecttothecitedparagraphsofthissection:*f8"Qdddd  dd ?"P(#(#f,dd , dd +   ` ID# '" 'APPLICABLEPARAGRAPH F<"  ?1?F1 F<1$T"  ?1 ? F60.115b(a) F<$T "  @2@F2 F<1!"  @2 @ F60.115b(b) F<""  @3@F3 F<1#"  @3 @ F60.115b(c)"$"  "  (iv)  60.116bMonitoringofoperations  %   Alltanksshallfollowthemonitoringrequirementsofboth60.116bandthoseset forthin D"t' themonitoringsectionofthispermit.  # )   XeX&&  CYTECTITLEVPERMITLIKEKINDREPLACEMENTSECTION#&&XXeS#% %&& H r f[ I.PURPOSE   ToestablishaprocedurethatallowsforthereplacementofanemissionsourcewithidenticalequipmentwithouttheneedforCytectoobtainaRCSA22a1743NSRpermitforthereplacement. II.APPLICABILITY   l  Thissectionappliestoalllikekindreplacementsofequipmentnotpreapprovedelsewhereinthispermitandnotsubjecttoanewapplicablefederallyenforceablerequirementnotaddressedinthepermit,solongasthefollowingconditionsaremet.AnychangethatdoesnotmeettheseconditionsissubjecttotherequirementsofRCSA22a1743andRCSA22a17433,asapplicable.(a)FutureActualEmissionsTestThedifferencebetweentheprojectedfutureactualemissionsofthereplacementandthecurrentactualemissionsofthereplacedunitmustbebelowstateandfederalpreconstructionthresholdlevels.Emissionincreasesatotheremissionsunitsresultingfromthereplacementshallbeincludedintheprojectedfutureactualemissionsofthereplacement.Futureactualemissionsshallbecalculatedbymultiplyingthenewemissionratebythecurrentutilizationrateortheprojectedutilizationrate,whicheverisgreater.(b)EmissionsDeterminationandMonitoringTheemissionsfromthereplacementunitcanbequantifiedandmonitoredusingmethodsprovidedforinthemonitoringsectionofthispermit.̜ III.FAILURETOCOMPLY  H Ifoverthelifeofthepermit,itisdeterminedthatthelikekindreplacementdidnotcomplywiththerequirementsofthissection,thelikekindreplacementwouldbecomesubjecttotherequirementsofRCSA22a1743asthoughconstructionhadnotcommenced.#&&%% #  <#" XeX&&Ԝ6f֛    CYTECTITLEVPERMIT H PLANTWIDEAPPLICABILITYLIMITATION(PAL)SECTION#&&XXe'#  < m I.PURPOSE   ToestablishafederalandstateenforceableVOCemissionslimitationforallVOCemittingactivitiesatCytecthatcomplieswiththerequirementsofConnecticutsSIPapprovedrulesforPALs.Onceestablished,subsequentphysicaloroperationalchangesmadeconsistentwiththePALwillnotberequiredtoobtainaRCSA22a1743NewSourceReview(NSR)permitforVOCemissionincreases,butinsteadwillbetrackedasdescribedbelow. II.APPLICABILITY    ̜Exceptforremediationactivitiestreatingcontaminationthatwasgeneratedbyaprocessnotrelatedtocurrentorplannedfutureactivities,thissectionappliestoallmodificationstoexistingemissionsunitsortheadditionsofnewemissionsunitsthatwouldresultinachangeinthesitesPTEforVOC,providedthefollowingconditionsaremet.AnychangethatdoesnotmeettheseconditionsissubjecttoRCSA22a1743andtheRCSA22a1433modificationrequirements,asapplicable.(a)0  Emissionsquantificationmethodsforthenewormodifiedemissionsunitsarecurrentlyapproved l$ intotheTitleVpermitasdescribedinthequantificationsectionofthispermit. (#(# (b)0  Emissionsmonitoringrequirementsforthenewormodifiedunitsarecurrentlyapprovedintothe  TitleVpermitasdescribedinthemonitoringsectionofthispermit. (#(# ̜(c)0  ThefollowingrequirementsshallapplytoPCDsusedforVOCcontrol:4(#(# 0  (i)0(#(#ModificationsAffectingPCDPerformance(#(# 0  0(#(#IfaproposedmodificationwouldaffecttheperformanceofanyPCDidentifiedinthisϜpermit,otherthanamodificationtothePCDitself,thenCytecshalldeterminetheemissionratefromthePCDthatwouldresultfromthemodificationpriortoimplementingthemodification.Thedeterminationofemissionrateshallbeconductedfollowingthemethodsdescribedintheemissionsquantificationsectionofthispermit.Notwithstandingtheaforementionedrequirement,DEPmayallowforatrialperiodofthemodificationforthepurposesofemissionstesting. (#(#   (ii)0  ModificationstoorReplacementofPCDEquipment"|'(#(#   0  CytecshallnotmodifyorreplaceanyPCDidentifiedinthispermitifthemodificationwillincreaseanticipatedactualVOCemissionsfromthesitebymorethantheminorNSRpermitmodificationthreshold. (#(# М0  [ThelanguageofII(c)(ii)hasbeenprovidedforillustrationandissubjecttorefinement.] (#(# Л0  (iii)0(#(#OperationofPCDEquipment$)%/(#(# 0  0(#(#CytecshalloperateanyPCDidentifiedinthispermitincompliancewithallapplicablerequirements,andinaccordancewithitsoperationandmaintenanceplan. (#(# ̜(d)0  VOCemissionsshallnotexceedthePALbaselineasdeterminedinconditionIII.# -)4(#(#  #Ї(e)0  Nonewapplicablefederalrequirementnotaddressedbythepermitistriggered.(#(#  III.DETERMINATIONOFPLANTWIDEEMISSIONSLIMITATIONSBASELINE  d (a)0  ThePALbaselineshallequalthetotal1990VOCemissionsforthepremiseplusthemajor   modificationthresholdlevelforVOCdefinedforthearea(25tpy). (#(# (b)0  Thetotal1990VOCemissionsshallequalthesumofthe1990RACTemissionsandthe1990  l nonRACTemissions.The1990RACTemissionsestimatesshallbedeterminedusing1990RACTreportedemissionsadjustedtoaccountforcurrentemissionestimationmethodsforeachreportedsourcetype(CYRO,ACMolding,ResinsandCentralServices).The1990nonRACTemissionsshallbedeterminedbyestimating1994nonRACTemissionsandextrapolatingthoseemissionsto1990foreachreportedsourcetype. (#(# 0  For1990RACTemissions: (#(# 0  1990RACTemissions=1990VOCRACTorderemissions*(1994adjustedRACTemissions/1994RACTorderemissions) (#(# 0  For1990nonRACTemissions: (#(# 0  1990nonRACTemissions=1994nonRACTVOCemissions*(1990adjustedRACTemissions/1994adjustedRACTemissions) (#(# 0  Total1990VOCemissions=1990RACTemissions+1990nonRACTemissions (#(# (c)0  Ifatanytimeduringthelifeofthispermitanadditionalrequirementbecomesapplicable(e.g.  IndustrialWastewaterACT),thePALbaselineshallbeadjustedbydeterminingtheamountofemissionreductionsthattheadditionalrequirementwouldhaveachievedifappliedduring1990andsubtractingtheemissionreductionsfromthePALbaseline.AnychangeinthePALresultingfromadditionalapplicablerequirementsdescribedinthispermitshallbeprocessedasaminorpermitmodificationconcurrentwithincorporationoftheadditionalrequirementsintothispermit. (#(# (d)0  Ifatanytimeduringthelifeofthispermitthestateapprovestheuseofarevisedquantification    methodforanemissionsunit,thePALbaselineshallbeadjustedbyrecalculatingthe1990baselineusingtherevisedquantificationmethod.AnychangeinthePALresultingfromϜquantificationmethodsrevisedconsistentwiththeemissionsquantificationsectionofthispermitshallbeprocessedasaminorpermitmodificationconcurrentwithincorporationoftherevisedemissionquantificationprocedureintothispermit. (#(# (e)0  ThePALbaselineatthetimeofpermitissuanceis_______tpy.IfduringthepermitlifeIII(c) % ' orIII(d)istriggered,thenthePALbaselineshallberecalculatedusingtheproceduredescribedinIII(b).AllfuturecompliancerequirementswillbebasedonthemostrecentPALbaselinevalue. (#(# (f)0  IfCytecsactualemissionsarelessthanthePAL,Cytecmaynotuseorprovidetoanyother )#, partythedifferenceasanemissionoffsetoremissionreductioncredit. (#(#  IV.NOTIFICATION  ,d&0  -<'1 МCytecshallnotifyDEPinwritingofanyactivityunderthissectionaminimumof30daysbeforeϜbeginningtheactivity.Thenotificationshallcomplywiththenotificationsectionofthispermit. V.COMPLIANCE   0 ActualVOCemissionsforCytecshallbecalculatedattheendofeachmonth.Themonthlyemissiontotalshallbeaddedtothetotalaggregatedactualemissionsoftheprevious11months.Theresultant12monthactualemissiontotalshallnotexceedthePALbaseline. VI.QUANTIFICATION  \  ̜Cytecshalldetermineemissionsunderthissectioninaccordancewiththequantificationsectionofthispermit. VII.MONITORING  0  ̜Cytecshallconductmonitoringunderthissectioninaccordancewiththemonitoringsectionofthispermit. VIII.EMISSIONSABOVETHEPAL  x (a)0  IfCytecappliespursuanttoRCSA22a1743toincreasethePALbaselineunderIII(e),the  proposedincreaseshallbesubjecttotheNSRrequirementsforamajormodification. (#(# (b)0  IfCytecviolatesthePALandcannotreduceitsemissionstobelowPALlevelswithinthree   months,theneachmodificationmadepursuanttothePAL,beginningwiththemostrecent,shallbesubjecttotheNSRrequirementsforamajormodificationunderRCSA22a1743untilactualemissionsdecreasebelowthePALbaseline.IfallmodificationsmadepursuanttothePALaresubjecttoNSRandtheemissionsremainabovethePALbaseline,thentheremainingamountofemissionsabovethePALbaselineshallbeoffsetataratioof1.2to1.IfnomodificationspursuanttothePALoccurredatthepremise,thentheamountofemissionsabovethePALbaselineshallbeoffsetataratioof1.2to1. (#(# (c)0  Notwithstandingtherequirementsof(a)and(b),anyemissionsabovethePALshallbea 8$% violationofthispermitandtheCleanAirAct. %x&(#(#      XeX&&6|CYTECTITLEVPERMITPOLLUTIONPREVENTION(P2)SECTION#&&XXe#  H   u I.P2PLAN   (a)Conditions̜Cytecshalldevelopandimplementapollutionpreventionplaninaccordancewiththeconditionsspecifiedbelow:0  (i)0(#(#CytecshallsubmitaproposedpollutionpreventionplantoDEPwithinsixty(60)daysof t ,  permitissuance. (#(# 0  (ii)0(#(#DEPwillreviewandcommentontheproposedplanwithinthirty(30)dayswithrespectto   programelementsspecifiedbelow. (#(# 0  (iii)0(#(#CytecshallsubmitwrittenresponsetoDEPscommentsandrecommendationswithinthirty <  (30)days.CytecshallincorporateDEPsrecommendationsorprovidejustification/explanationforrejectingtherecommendations. (#(# 0  (iv)0(#(#DEPwillnotifyCytecwithinthirty(30)daysastothepollutionpreventionplanapproval l$ status. (#(# 0  (v)0(#(#TheP2Planshallbecontainedoutsideofthispermit.Therequirementtohaveaplan  containingtheelementslistedbelowshallbetheonlyrequirementofthispermit.Thedetailsoftheplanitselfshallnotbeenforceable.Revisionstothisplanwillnottriggerpermitmodificationsandaninadequateplanwillnotcauseapermitviolation. (#(# 0  (vii)0(#(#CytecshallmakepublicitsP2effortsbyconductingpublicoutreachmeetingsannually.(#(# (b)ElementsTheP2planshallinclude,butnotbelimitedto:0  (i)  CorporatestatementofcommitmentL"(#(# 0  (ii)  Pollutionpreventiondefinition, $(#(# 0  (iii)  Employeetrainingandrecognitionprogram!|&(#(# 0  (iv)  Existingandnewprocesspollutionpreventionreviewprocedures\# ((#(# 0  (v)  Communityoutreach$!*(#(# 0  (vi)  Productstewardship/customerandsupplieroutreachandrecognitionprogram&D#,(#(# 0  (vii)  Environmentalreviews/audits$($.(#(# 0  (viii)  Benchmarking/plantkeyperformanceindicators)t&0(#(# 0  (ix)  PollutionpreventionmetricsT+ (2(#(# 0  (x)  Reporting/trackingprocedures,)4(#(#  -p*5 Ї II.P2COMPONENTOFBACTDETERMINATIONS   (a)PurposeToestablishaprocedurethatallowstheuseofpollutionpreventiontomeetaBACTlimit.ThissectiondoesnotpreapproveaBACTlevelforCytec.(b)ApplicabilityPollutionpreventionmaybeconsideredinallBACTreviews.CytecshallperformtheBACTanalysisasdescribedbelow.(c)BACTDeterminationApproach0  (i)0(#(#CytecshallconductaBACTanalysis,ifrequiredbyRCSA22a1743,inthefollowing 4  manner: (#(#   0  (A)0` (#(#Forsourcesbeinginstalledwithpotentialemissionsoflessthanminornewsource h  reviewthresholds,BACTshallbesatisfiedwhenCytecmakesreferenceofaBACTdeterminationforasimilaroridenticalsourcemadewithinthelastfiveyears,andwhichappearsinthemostrecentRACT/BACT/LAERClearinghouse. ` (#` (#   0  (B)0` (#(#Forsourcesbeinginstalledwithpotentialemissionsgreaterthanminornewsource d reviewthresholds,aBACTreviewshallbeconductedinaccordancewiththemostrecentDEPguidance. ` (#` (#     (C)0 ` Forsourcesbeinginstalledwithpotentialemissionsgreaterthanmajornewsource  reviewthresholds,aBACTreviewshallbeconductedinaccordancewiththemostrecentDEPandEPAguidance,incorporatingthemorestringentguidanceifdiffering. ` (#` (# 0  (ii)0(#(#UponDEPreviewandapproval,CytecmaysatisfytheBACTrequirementsdeterminedin  (i)throughimplementationofanycombinationofthefollowingmeasures: (#(#   0  (A)0` (#(#Pollutionpreventionattheproposedsource( X!` (#` (# 0  0(#(#(B)0` (#(#Pollutionpreventionatadifferentsource(s)(forminornewsourcereviewpurposes !# only), ` (#` (#   0  (C) ` Airpollutioncontrols.$$T&(#(#   0  (iii)0(#(#Theemissionreductionsachievedthroughpollutionpreventionshallbepermanent,real, T'!* andquantifiable.OnlytheoffsetofidenticalpollutantsthroughpollutionpreventionshallbeconsideredinBACT. (#,(#(#   u  XeX&&CYTECTITLEVPERMIT  ԀREMEDIALACTIVITY >ԀSECTION#&&XXe #  H Ӝ I.PURPOSE   Thissectiondescribesthecriteriafordeterminingwhetheremissionsfromaremedialactivitycanbeconsideredseparatefromemissionsassociatedwithotheroperationsatthesitewithregardtosignificantmodificationdetermination,andifsohowairpollutantemissionsfromtheremedialactivitywillbeaddressed. II.APPLICABILITY  @   Airpollutantemissionsfromremedialactivitiesrelatedtocleanupofmaterialreleasedfromaprocess notincludedinthePALbaselineand notrelatedtoanycurrentoranticipatedoperationsat h  thesitewill not beconsidered independentlyfromtheprimarysite withregardtomajormodification |4  determination. Thedeterminationdescribedabovewillbebasedonthechemicalsinvolvedinthe H  remediation,thelocationofthecontaminatedmaterial,andoperatorknowledgeofthesourceoftherelease. Cytecmustperformemissioncalculationsandanairpollutantevaluationforsuchremedial  activities as are describedinsubsectionsIIIandIV.Emissionsfromallotherremedialactivitieswill d beincludedwithemissionsfromtherestofthesite,includingconsiderationunderanyPAL.̛̜  III.EMISSIONCALCULATIONS     ̜Cytecwillestimatethemaximumexpectedemissionsassociatedwitharemedialactivityconsistentwiththeemissionsquantificationsectionofthispermitpriortocommencingoperation.Ifnewinformationisobtainedduringthecourseoftheremedialactivitythatcouldaffectemissions,themaximumexpectedemissionswillbereestimated.̜  IV.AIRPOLLUTANTEVALUATION    H (a)0  Cytecwillkeepdocumentationneededtoshowcompliancewiththerequirementstocontrol ! hazardousairpollutantsunderRCSA22a17429.IfaMASCwouldbeexceededforaTable1compound,thenCytecshallobtainwrittenapprovalfromDEPpriortocommencingtheplannedremedialactivity,unlessanimminenthealthhazardneedstobeaverted. (#(# (b)0  Iftheestimatedairpollutantemissionsassociatedwithaplannedremedialactivityexceedthe !& permitapplicabilitylevelsestablishedinRCSA22a1743,Cytecshallperformalltasksthatwouldberequiredforanewsourcereviewpermitapplication,priortocommencingtheplannedremedialactivity,unlessanimminenthealthhazardneedstobeaverted. (#(# (c)0  Ifanimminenthealthhazardneedstobeaverted,theactionsrequiredundersubsections(a)and %"+ (b)willbeperformedassoonaspractical. #&h#,(#(#: #     XeX&&CYTECTITLEVPERMITNOTIFICATIONSECTION#&&XXee#% %&& H 7~I.SEVENDAYNOTIFICATION   (a)0  CytecshallnotifyDEPinwritingwithinsevendaysofthefollowing:H(#(#   (i)0  Determiningthatanemissionsunitmeetsthecosteffectivenesscriteriaassetforthinthe (  BatchProcessesACTasspecifiedintheapplicablerequirementssectionofthispermit. (#(# (b)0  CytecshallnotifyDEPinwritingatleastsevendayspriortothefollowing: D (#(# 0  (i)0(#(#Installationofairpollutioncontroldevicesforemissionsunitsdeterminedtomeetthecost $  effectivenesscriteriaassetforthintheBatchProcessesACTasspecifiedintheapplicablerequirementssectionofthispermit. (#(# 0  (ii)0(#(#Additionorremovalofanemissionsourceventedtoanairpollutioncontroldevice T  registeredundertheemissionslimitationsectionofthispermit. (#(# 0  (iii)  Preapprovednewsourcereviewchangesprovidedbythispermit.p(#(# 0  (iv)0(#(#Registrationofairpollutioncontroldevicesprovidedintheemissionslimittaionsectionof P thispermit. (#(# 0  (v)0(#(#Registrationofonanoperationallimitationprovidedintheemissionslimitationsectionof l thispermit. (#(# 0  (vi)0(#(#Registrationofonapollutionpreventionmeasureprovidedintheemissionslimitation  sectionofthispermit. (#(# #&&%% #% %&&0  (vii)0(#(#Initiationofanemissionsaveragingplanprovidedbythispermit.#&&%% 7#ԛ|4(#(# 0  (viii)0(#(#Installation/modificationofanyemissionsunitcoveredbythePALprovisionsasspecified   inthePALsectionofthispermit. (#(# Followingnotification,Cytecshallcomplywiththerequirementsspecifiedinsaidnotification.Eachsuchnoticeshallbeattachedtothispermitandbeenforceableasanadministrativeamendmenttothispermit.% %&&ԛ !%  II.THIRTYDAYNOTIFICATION t#, (  Atleastthirtydayspriortoinitiatingthefollowingactions,CytecshallnotifyDEPinwritingofsuch $%!* intendedactions:(a)0  InitialstartupofanaffectedfacilitywhichissubjecttoaNewSourcePerformanceStandardin '@$- 40CFR60,aNationalEmissionStandardforHazardousAirPollutantsin40CFR61or63,orisa112(g)sourceper40CFR63SubpartB,asspecifiedintheapplicablerequirementssectionofthispermit. (#(# ̜(b)0  Performemissiontestingrequiredtodemonstratecompliancewithanapplicablerequirement; +<(2 ortodemonstrateairpollutioncontrolefficiencypursuanttothequantificationsectionofthisϜpermit. (#(#  -*5  (c)0  Initialstartupof"likekind"replacementsasspecifiedinthelikekindreplacementsectionofthis  permit. (#(# (d)0  Creationofanoperationandmaintenanceplan,andrevisionstosuchplan,forairpollution 4d controldevicesregisteredundertheemissionslimitationsectionofthispermit. (#(# Followingnotification,DEPwillhavethirtydaystorespondtotheinformationcontainedinthenotificationandidentifyanyobjections.#&&%% #IfanobjectionisraisedbyDEP,thenCytecshallreviseand d  resubmitthenotificationtoaddresstheobjection.Oncenotificationhasbeensubmittedwithoutobjection,Cytecshallcomplywiththerequirementsasspecifiedinsaidnotification.Eachsuchnoticeshallbeattachedtothispermitandshallbeenforceableasanadministrativeamendmenttothispermit.% %&&ԛ    III.INFORMATION  (  NotificationssubmittedtotheDEPshallcontainthefollowinginformation,asapplicable:(a)  Equipmentidentificationanddescription 4d (b)  Emissionsunitidentificationanddescription  (c)  Locationofthenew/modifiedequipment/emissionsunit d (d)  Anticipateddateofcompletionofconstruction/modification , (e)  Anticipateddateofcommencementofoperation  (f)  Compliancemethodologyprovidedinthispermit ,\ (g)  Quantificationmethodologyprovidedinthispermit  (h)  Monitoringmethodologyprovidedinthispermit \  (i)  Recordkeepingrequiredbythispermit  $" (j)  Reportingrequiredbythispermit "$ (k)  Anticipatedemissionsofeachpollutant $$T& М#&&%% "#(l)0  CitationsofthespecificproposedMACTstandardsCytecisusingasthebasisforthe112(g) %( MACTdeterminationandwithwhichCytecshallcomply. (#(# 9,Xw` X,X X9̜(m)0 ' Forlikekindreplacements,currentactualemissionsofthereplacedunitandthebasisforthe  (P"+ projectfutureactualemissions. '(#'(# 9,X X,Xw` X9 IV.NEWAPPLICABLEREQUIREMENTS  P+%/ ̜CytecshallprovidenotificationtoDEPinaccordancewithallnewapplicablerequirementstowhichϜCytecbecomessubjectduringthetermofthispermit.Cytecshallobtainallnewsourcereview -'2 permitsandTitleVmodificationsnecessarytoauthorizeoperationunderthenewapplicableϜrequirements. XeX&&ԛ      t CYTECTITLEVPERMITRECORDKEEPINGSECTION#&&XXe)#% %&&  H #&&%% *#.*  *~̜% %&&Cytecshallrecordthetotalemissionsofeachpollutantemittedfromanemissionsunitthatisneeded  tomeetanemissionlimitthatispartofanapplicablerequirement,orwhichisrelieduponindemonstratingthatarequirementisnotapplicable.Thecalculationofemissionsshallbedeterminedusingtheapplicablequantificationandmonitoringmethodologyspecifiedinthispermitforeachemissionsourceandcontrolequipmentcombination.Foreachrequirementlistedbelowthefollowingrecords#&&%% 2+#% %&&shallbemadeandkeptatCytecforatleastfiveyearsfromthedatesuchdataand   informationwereobtained#&&%% -#% %&&,andshallmadebeavailabletoDEPuponrequest#&&%% L.#% %&&:#&&%% .#ԛ  T   I.VOCRACTORDER8012 Therecordkeepingrequirementsforthebatchprocessventswhicharenotrequiredbytheorderto   achieve85percentcontrol,aresupersededwiththeBatchProcessesACTrecordkeepingrequirementsdescribedbelow.ThefollowingrecordkeepingrequirementssupersedetherequirementsofStateOrderNo.8012.̜(a)CarbonAdsorptionUnits  (i)  Actuallifeofeachcarbonbed \   (ii)  Carbonadsorptionairflowrate    (iii)  Inletvaporstreamtemperatureduringtheadsorptioncycle D   (iv)  Lengthofalldesorptioncycles $   (v)  Allmonitoringdata,testdata,andcalculationsusedtoconfirm85percentcontrol t (b)Scrubbers  (i)  Operationandmaintenanceplan !   (ii)  Preventivemaintenance,breakdowns,andrepairsshallbedocumentedasto: <# ̀  (A)Lengthofcontrolequipmentshutdown !%     (B)AmountofVOCemitteduncontrolledifany !&     (C)Descriptionoftheproblemarea "l'     (D)Typeofrepairsperformed #8 (     (E)Apreventivemaintenancescheduletoavoidfuturefailure L$!)   (iii)  Allmonitoringdata,testdata,andcalculationsusedtoconfirm85percentcontrol %"+   |'4$-  (c)EmissionControlCondensers0  (i)0(#(#Automaticallyrecordedtemperatures,onlyduringtimeofexcursions,byacondenservent h monitoringsystemutilizingtripalarms (#(# 0  (ii)0(#(#Allcalculationsusedtoconfirmthealarmsetpointsensuringaminimumof85percent   control (#(# (d)MurrayM64SeriesBoiler(BoilerNo.4)̀ThefollowingrecordsshallbemaintainedifVOCliquidwastesarecombustedintheboiler:  (i)  Twohourintervalstacktemperatures `    (ii)  DailyrecordsoftheamountofVOCconsumed (    (iii)  AnnualrecordsoftotalVOCsenteringanddestroyedintheboiler   0  (iv)0(#(#Allmonitoringdata,testdata,andcalculationsusedtoconfirmaminimum90percent (X destructionefficiency (#(# (e)VOCFugitiveEmissionControlProgram  (i)  LeakDefinition $T   (ii)  Equipmenttobeinspected    (iii)  Inspectionmethods T   (iv)  Inspectionfrequency    (v)  Correctiveactionswhenleaksoccur   II.BATCHPROCESSESACT  !# ̜(a)  Emissionpointidentification d#% (b)0  Emissionsunitcontainingbatchprocessfromwhichemissionpointisvented$,'(#(# Л(c)0  Annualmassemissionstotalinlb/yr,asdefinedbytheBatchProcessesACT,and & ) documentationverifyingtotal (#(# (d)0  Annualaverageflowrateinscfm,asdefinedbytheBatchProcessesACT,anddocumentation ((#, verifyingaverage (#(# (e)0  Foruncontrolledemissionpoints,themaximumflowrateatwhichcontrolwouldbecosteffective \+%/ asdefinedbytheBatchProcessesACT (#(# (f)0  Allmonitoringdata,testdata,andcalculationsusedtoconfirm90percentcontrol-'2(#(#  III.EMISSIONSAVERAGING  L| ̜(a)0  Identificationanddescriptionoftheemissionsourcesthatwillcomprisetheemissionsaveraging   plan (#(# (b)0  EmissioncalculationsquantifyingtheRACTequivalentemissionlimitation,includingthe T  averagingperiod (#(# (c)0  Calculationsofthetotalactualemissionrate (#(# (d)0  Monitoringmethodsanddataemployedtodeterminethetotalactualemissionrate,consistent P  withthemonitoringsectionofthispermit (#(# (e)0  AnycalculationsrequiredtodemonstratecompliancewithRCSA22a17429 (#(#  IV.NOXRACTORDER8114  H ̜(a)  Boilers  Thefollowingrecordsshallbemaintainedonamonthlybasis:  (i)  Heatinput    (ii)  NOXemissions    (iii)  CreditsanddebitsgeneratedforNOXemissionsaveraging L ̜(b)  SludgeIncinerator,HotOilFurnace,andSprayDryer  Thefollowingrecordsshallbemaintainedonamonthlybasis:  (i)  Hoursofoperation !#   (ii)  NOXemissions |#%   (iii)  CreditsanddebitsgeneratedforNOXemissionsaveraging %D' (c)  Other & ) 0  (i)0(#(#Documentationregardingthenumberofdiscreteemissionreductions(DERs)inCytecs D(t"+ possessionandusedeachmonth,aswellasinformationtoattesttothefactthatDERsusedduringtheozoneseasonweregeneratedduringtheozoneseason. (#(# 0  (ii)0(#(#AnnualreportonNOXemissionsforeachunitincludedintheNOXemissionsaveraging t+%/ plan,andthequantityoffuelconsumed,bytype,duringthepreviouscalendaryear.Eachannualreportshallincludeademonstrationthatcompliancewiththeconditionsoftheorderwasachievedforeachmonthandwiththeannualemissionlimitintons.-(2(#(#  V.EMISSIONS{VREDUCTION{V|VLIMITATION|VREGISTRATION t  (a)0  Identificationanddescriptionoftheregisteredemissions}Vreduct}VV~VLIMIATIO~VVVlimitationVVionV H(#(# (b)0  Identificationanddescriptionofallaffectedemissionsources (#(# (c)  Operationandmaintenanceplanforeachaffectedcontroldevice H x (d)0  Informationdescribinganyprocess/equipmentdesignselectedthatinherentlyreducespollution    formation (#(# ̛̜ VI.EMISSIONSQUANTIFICATION    Unlessotherwiserequiredbythispermit,Cytecshallmaintainrecordsofallrequiredemissionsquantificationdataandsupportinginformation.Supportinginformationshallincludeasapplicable:̜(a)0  theemissionsourceIDanddescription(#(# (b)0  theemissionsunitIDanddescription|(#(# (c)0  thecontroldeviceIDanddescriptionD(#(# ̜(d)0  theemissionsquantificationmethodusedtodetermineemissions(#(# ̜(e)0  thedate,place,andtimeofsamplingormeasurements;Dt(#(# (f)0  thedate(s)analysesofsuchsamplesormeasurementswereperformed; (#(# (g)0  theentitythatperformedtheanalyses;t (#(# (h)0  theanalyticaltechniquesormethodsusedforsuchanalyses; !<"(#(# (i)0  theresultsofsuchanalyses;"$(#(# (j)0  theoperatingconditionsatthetimeofsuchsamplingormeasurement;and<$l&(#(# (k)0  allcalibrationandmaintenancerecordsrelatingtotheinstrumentationusedinsuchsamplingor % ( measurements,alloriginalstripchartrecordingsorcomputerprintoutsgeneratedbycontinuousmonitoringinstrumentation,andcopiesofallreportsrequired.]&&&&Ԁ#&&&]&S# l'!*(#(#  VII.EMISSIONSMONITORING  ) $- Unlessotherwiserequiredbythispermit,Cytecshallmaintainrecordsofallrequiredmonitoringdataandsupportinginformation.Supportinginformationshallincludeasapplicable:̜(a)0  theemissionsourceIDanddescription-(2(#(# Ї(b)0  theemissionsunitIDanddescription(#(# (c)0  thecontroldeviceIDanddescriptionh(#(# (d)0  thetypeofmonitoring,whichmayincluderecordkeeping,bywhichsuchdatawasobtained; 0(#(# (e)0  thedate,place,andtimeofsamplingormeasurements; (#(# (f)0  thedate(s)analysesofsuchsamplesormeasurementswereperformed;0 `(#(# (g)0  theentitythatperformedtheanalyses;  (#(# (h)0  theanalyticaltechniquesormethodsusedforsuchanalyses;` (#(# (i)0  theresultsofsuchanalyses;( (#(# (j)0  theoperatingconditionsatthetimeofsuchsamplingormeasurement;and (#(# (k)0  allcalibrationandmaintenancerecordsrelatingtotheinstrumentationusedinsuchsamplingor (X measurements,alloriginalstripchartrecordingsorcomputerprintoutsgeneratedbycontinuousmonitoringinstrumentation,andcopiesofallreportsrequired.]&&&&Ԁ#&&&]&~Y# (#(# ̜% %&&VIII.LIKEKINDREPLACEMENT  Hx М(a)0  Equipmentidentificationanddescription(#(# (b)0  Emissionsunitidentificationanddescription(#(# (c)0  ActualemissionsofthereplacedunitL(#(# (d)  Actualemissionsofthereplacement   IX.PAL !H"  ̜(a)  Emissionsourceidentificationanddescription "$ (b)  Emissionsunitidentificationanddescription T$& #&&%% Y#(c)0  The12monthrollingaverageemissionrateofeachVOCemitted% ((#(# (d)0  Thecumulative12monthrollingaverageemissionrateofallVOCemittedfromCytec'!*(#(#  X.OTHERREQUIREMENTS  )$$- ̜Allnoticessubmittedpursuanttothenotificationsectionshallbeattachedtothispermitduringtheentirepermitterm,includinganyextensions. 0-`'1 [Thissectionwillbefurtherdevelopedatalaterdate.]    L|    c XeX&&֜CYTECTITLEVPERMIT  REPORTINGREQUIREMENTS %_ԀSECTION #&&XXe^# H ^  I.MONITORINGREPORTS _   (a)0  CytecshallsubmitwrittenmonitoringreportstotheCommissionereverysixmonths.The x0 monitoringreportshallprovidethefollowing: (#(# 0  (i)0(#(#thedateanddescriptionofeachdeviationcausedbyupsetorcontrolequipmentfailures,   eachdeviationfromapermitrequirement,andeachviolationofapermitrequirementthathasbeenmonitoredbythemonitoringsystemsrequiredundertheTitleVpermit,whichhasoccurredsincethedateoflastmonitoringreport;and (#(# 0  (ii)0(#(#thedateanddescriptionofeachoccurrenceofafailureofthemonitoringsystemtoprovide   reliabledata. (#(# (b)0  AnymonitoringreportsubmittedtotheCommissionerpursuanttothissubsectionshallbe <  certifiedinaccordancewithRCSA22a17433(b)(4). (#(#   II.PROGRESSREPORTSANDCOMPLIANCECERTIFICATIONS c l$ (a)0  Asnecessary,CytecshallsubmitprogressreportstotheCommissionereverysixmonthswhich  arecertifiedinaccordancewithsubdivisionRCSA22a17433(b)(4)whichreportCytecprogressinachievingcomplianceunderthecompliancescheduleinthispermit.Suchprogressreportshall: (#(# 0  (i)0(#(#identifythoseobligationsunderthecomplianceschedulewhichtheCytechasmet,andthe   datesbywhichtheyweremet;and (#(#   (ii)0  identifythoseobligationsunderthecomplianceschedulewhichCytechasnotmetina p( timelymanner,explainwhytheywerenotmet,describeallmeasurestakenortobetakentomeetsuchobligationsandidentifythedatebywhichtheCytecexpectstomeetsuchobligations. (#(# (b)0  CytecshallsubmitwrittencompliancecertificationstotheCommissionerevery12monthswhich l$# arecertifiedinaccordancewithRCSA22a17433(b)(4)thatidentifythetermsandconditionscontainedinthispermit,includingemissionlimitations.Inaddition,acompliancecertificationshallcontainthefollowing: (#(# 0  (i)0(#(#ameansformonitoringthecomplianceofthesubjectsourcewithemissions  @  @  @ limitations, h# ( standards,andworkpractices; (#(# 0  (ii)0(#(#theidentificationofeachpermittermorconditionwithrespecttowhichthe  @  @  @  %"+ certificationisbeingmade; (#(# 0  (iii)0(#(#compliancestatuswithrespecttothispermit;0($.(#(# 0  (iv)0(#(#whethercompliance,withrespecttothispermit,wascontinuousor x   @  @  @  @  @  @  @  @  @  @  @  @  @  @  @  @  )&0 intermittentsincethedateofthepreviouscompliancecertification; (#(# 0  (v)0(#(#themethod(s)usedfordeterminingcompliancestatus,currentlyandsincethedateofthe ,,(3 previouscompliancecertification; (#(#  -|*5  0  (vi)0(#(#suchotherinformationasthispermitmayrequiretofacilitatetheCommissioners  determinationofthecompliancestatusofsuchsource,andadditionalrequirementsspecifiedpursuantto40CFRPart70;and (#(# 0  (vii)0(#(#whetherthemonitoringsystem,whichmayincluderecordkeeping,wasfunctioningin  0 accordancewiththispermitandRCSA22a17433(q). (#(# (c)0  AnyprogressreportpursuanttoRCSA22a17433(q)(1),orcertificationsubmittedpursuantto d  RCSA22a17433(q)(2)totheCommissionershallalsobesubmittedtotheAdministrator. (#(# ̜ III.DEVIATIONS    Within7daysofbecomingawareofadeviationfromthetermsandconditionsofthispermit,CytecshallreportsuchoccurrencetoDEP.  4  7&&d&&d7   XeX&&APPENDIXA  H  AIRPOLLUTANTEMISSIONSESTIMATIONMETHODSFORBATCHPROCESSES n #&&XXe|r#[rr̜ Cytecestimatesbatchprocessairemissionsusingengineeringcalculationsperformedinadetailedandrigorousmannerusingequationsshownintheattachment[tobeprovided].Ascanbeseen, L theequationsusedareessentiallyidenticaltothosedetailedinOAQPSGuidelineSeriesControlofVolatileOrganicEmissionsfromManufactureofSynthesizedPharmaceuticalProducts,EPA450/278029.Emissionsfromnewproductswillbelikewiseestimatedusingthesamefundamentalequationsandtechniques.Overallfacilityemissions,consistingofbatchprocessmodelsandotheremissionestimationtechniques,resideinasoftwaredatabase.Batchprocessrecipestepsaredevelopedusingtheamountcharged,temperatures,stepdurations,andequipmentusedfromactualbatchproductionsheets.EmissionsfromeachstepineachrecipeareestimatedusingequationsshownintheϜattachment.Vesselcleanups,batchrestrips,andtankthroughputsarealsoincludedinthebatchprocessmodel.Furthermore,theprocessequipmentpresentattheCytecWallingfordfacilityhasbeenfullydescribedandlinkedwithassociatedpollutioncontroldevicesandemissionpointsineachmodel.Anynewequipmentwhichmaybeaddedinthefuturewillbesimilarlydescribedandlinked.̀Inordertoincreasetheestimationaccuracyduetovaporliquidequilibriaofhighlynonidealmixtures,proprietarymulticomponentdistillationprocessdesignsoftwareisutilizedtopredictvaporcompositionsabovedifferentliquidmixturesatdifferenttemperatures.Thissoftwareuseswellrecognizednumericaltechniquestoaccuratelyaccountfortheinteractionofendgroupsofvariouschemicalspeciespresent.Othersourcesofinformationforthebatchprocessmodelsincludeequipmentmanufacturersdesignspecificationsandsourcetestingpreviouslyperformedforcomplianceassurance.Inordertocalculatetheemissionsforagiventimeperiodorforagivennumberofbatchesofspecifiedproducts,Cytecneedsonlytoinputthenumberofbatches,cleanups,restrips,andtankthroughputsintothedatabase.Thedatabasethencalculatesspeciatedpollutantdischargeamountsfortheemissionpoints.Asequipmentchangesaremadeornewrecipesareformulated,thelinkagesareupdatedand/ornewmodelsarecomposedusingthesamefundamentalequationsandmethodologyemployedforexistingequipmentandrecipes.  # hHhHHH UUUUUUUUUUUU    XX&&%APPENDIXB  h  AIRPOLLUTANTEMISSIONSESTIMATIONMETHODSFORREMEDIALACTIVITIES#&%&XXFx#܆&&%  h :xex*f"dddd  dd 8"QH$H$f,dd ,dd ,dd +    XREMEDIALACTIVITY   МDESCRIPTION  D EMISSIONESTIMATIONMODEL (D  X0  X(  INSITUGROUNDWATERTREATMENT +!   X0  X+AirSparging  $   Extractionofcontaminantsbyforcedairinjection. 4* $   ?1?41 >4.$   ?1 X0 ? X>Bioremediation  `  Injectnutrients/oxygentoenhancenaturalbiodegradationoforganics. 4* `   @2@42 B8.`   @2 X0 @ XBz  EXSITUGROUNDWATERTREATMENT +! 4   X0  X+|AirStripping   p  Removalofvolatilesbypassingthroughairstream. 4*  p   @3@43 >4. p   @3 X0 @ X>Bioremediation    Removaloforganicsinbioreactor. 4*    @4@44 >4.   @4 X0 @ X>CarbonAdsorption  P  Removaloforganicsincarbonbedcolumn.  P  Confirmnosourceofemissions P X0 XUVTreatment   UVlightbombardmentintransparentchamber.    Confirmnosourceofemissions #\# X0 X#  INSITUSOILTREATMENT +!0$  X0  X+AirSparging  l% Extractionofcontaminantsbyforcedairinjection. 4* l&  ?1?41 >4.l'  ?1 X0 ? X>Bioremediation  ( Biodegradationoforganicconstituentsbyindigenousmicroorganismsaidedbyinducingairflowandaddingnutrients. 4* \*  @2@42 >4.+  @2 X0 @ X>PlasmaArcInjection  , Passinghighenergyplasmaarcthroughcontaminatedsite.  - ManufacturersDataUUURUUUUUUUUU ,#  1      L/ X0 XSoilVaporExtraction  0 Extractionofsoilvaporusingpressuregradient. 4* 1  @5@45 B8.2  @5 X0 @ XB  EXSITUSOILTREATMENT +!,3  X0  X+Bioremediation  h4 Extractionofsoilwithsubsequenttreatmentinabioreactor. 4* h5  @6@46 >4.h6  @6 X0 @ X>Combustion  <7 Combustionofextractedvolatiles. 4* <8  @7@47 >4.<9  @7 X0 @ X>Composting  x: Excavationofsoilandtransferontopileswithinwhichmicrobialgrowthisstimulationbyaerationandadditionofminerals,nutrients,andmoisture. 4*  ,<   @8 @48 >4.x=   @8 X0  @ X>Removal/TransportOffSite  "!? Extractionofsoilwithsubsequentshipmentoff-site. 4* !h @   @8 @48 >4.!h A   @8 X0  @ X>Solidification/Stabilization  t$ #C Extractionofsoilwithsubsequentmixingwithstabilizingchemicalstopreventpollutantmigration. 4* t$ #E   @8 @48 >4.#X"F   @8 X0  @ X>ThermalDestruction  %H$G Destructionofcontaminantsinsoilbyexposuretotemperaturestypicallywithinrangeof1500Fto2000F. 4* d&$I  @7@47 >4.%H$J  @7 X0 @ X>ThermalDesorption  '8&K Volatilizationofcontaminantsfromsoilbyexposuretotemperaturestypicallywithinrangeof500Fto900F. 4* T(&M  "@9"@49>42'8&N  "@9 X0  "@ >М  8)'N HhHh&%&܆@// DESCRIPTIONSOFMODELS   MODEL1: t Description:AqueousSystemwithOffGassingEquation0 t 06t$t$06$6$ER= P QHC1.0 $$  t  6    P RT t where:0  ER P = emissionrate[g/s]n  $$  t  6   Q P = offgasrate[m3/min] H   t  6   H P = HenrysLawconstant[atm m3/mole] "^   t  6   C P = concentrationofcontaminantinwater[mg/liter] 8   t  6   R P = gasconstant[8.206x105atm m3/mole K]    t  6   T P = absolutetemperature[K]    t  6   1.0 P = conversionfactor[g/mgtoliters/m3]    t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries >z ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section4.4, T March1993. $$  t Assumptions: P None  MODEL2: t Description:BioventingEmissionsEquation t  6   ERAVG=(M)(BE/100)/t=SvC(BE/100)(1.0)/t   t where:  ERAVG P = averageemissionrateofcontaminanti[g/s] P  t  6   M P = totalmassofcontaminantiinsoil[g] * f  t  6   BE P = bioremovalefficiency[%],typically80to90percent !@   t  6   t P = durationofremediation[s] !!  t  6   Sv P = volumeofcontaminatedsoiltobetreated[m3] ""  t  6   C P = averageconcentrationofcontaminantiinsoil[g/g] ##  t  6    P = bulkdensityofsoil[g/cm3] l$$  t  6   1.0 P = conversionfactor[g/cm3tog/m3] F%%  t  t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries &6!' ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section3.2, '"( March1993. $$  t Assumptions:0 P Defaultbioremovalefficiency=85percentb*$+P $P $   ,R&- MODEL3: t Description:AirStripperMassBalanceEquation0 t  6 0t$t$ER=CL(SE/100)(1.67x105), h$$  t where:  ER P = emissionrateofcontaminanti[g/s]    t  6   C P = concentrationofcontaminantiinwater[mg/L]    t  6   L P = influentflowrate[liters/m]    t  6   SE P = strippingefficiency[%] n    t  6 1.67x105 P = conversionfactorfrom[mg/m]to[g/s] H   t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries 8  ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section3.1,   March1993. $$  t Assumptions:0 P StrippingefficiencycanbedeterminedbasedonHenrysLawconstantsas d  describedintheIndustrialWasteWaterACT. P $P $ MODEL4: t Description:BioslurryProcessEquation0 t 06t$t$06$6$ER= P (Q/60)(C/1000)(V/100)4p$$  t where:0  ER P = emissionrateofcontaminanti[g/s]$$$  t  6   Q P = volumerateoftreatedslurry[liters/min]   t  6   C P = concentrationofcontaminantiinslurry[mg/liter]   t  6   V P = percentageofcontaminantivolatilized[%] v  t  6   60 P = conversionfactor[s/min] P  t  6   1000 P = conversionfactor[mg/g] * f  t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries !! ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section4.4, "" March1993. $$  t Assumptions:0 P PercentagevolatilizedcanbeapproximatedbasedonHenrysLawconstantas F%% describedinSection4.4ofthecitedsourcedocument.IfnoHenrysLawconstantisavailableassume80%isvolatilized. P $P $   (") MODEL5: t Description:SoilVaporExtraction t  6   ERAVG=M/t=SvC(1.0)/t , h  t where:  ERAVG P = averageemissionrateofcontaminanti[g/s]    t  6   M P = totalmassofcontaminantiinsoil[g]    t  6   t P = durationofremediation[s]    t  6   Sv P = volumeofcontaminatedsoiltobetreated[m3] n    t  6   C P = averageconcentrationofcontaminantiinsoil[g/g] H   t  6    P = bulkdensityofsoil[g/cm3] "^   t  6   1.0 P = conversionfactor[g/cm3tog/m3] 8   t  t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries   ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section3.2,   March1993. $$  t Assumptions:0 P NoneTP $P $ MODEL6: t Description:BioslurryProcessEquation0 t 06t$t$06$6$ER= P (Q/60)(C/1000)(V/100)J$$  t where:0  ER P = emissionrateofcontaminanti[g/s]$$  t  6   Q P = volumerateoftreatedslurry[liters/min]   t  6   C P = concentrationofcontaminantiinslurry[mg/liter] v  t  6   V P = percentageofcontaminantivolatilized[%] P  t  6   60 P = conversionfactor[s/min] * f  t  6   1000 P = conversionfactor[mg/g] !@   t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries "" ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section4.4, ## March1993. $$  t Assumptions:0 P PercentagevolatilizedcanbeapproximatedbasedonHenrysLawconstantas  &\ & describedinSection4.4ofthecitedsourcedocument.IfnoHenrysLawconstantisavailableassume80%isvolatilized. P $P $   )#* MODEL7: t Description:ThermalDestructionEquation0 t 06t$t$06$6$ER= P 0.278x106FTC(1DRE/100), h$$  t where:  ER P = emissionrateofcontaminanti[g/s]  B  t  6   FT P = totalfeedrateofmaterialtreated[kg/hr]    t  6   C P = concentrationofcontaminanti[g/g]    t  6   DRE P = destructionandremovalefficiencyofcontaminant[%]    t  6 0.278x106 P = conversionfactor[g2 hr/kg g s] n    t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries "^  ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section3.3, 8  March1993. $$  t Assumptions:0 P DestructionandremovalefficiencycanbeapproximatedasdescribedinSection   3.3ofthecitedsourcedocument. P $P $ MODEL8: t Description:ExcavationEquation0 t 06t$t$06$6$ER= P ERDIFF+ERPS$$  t  6   ERDIFF= 򀀀(CS)(10,000)(SA) 4p  t  6    P  1.22x106(CS/P)+(1.79x109(CS/P)) J  t  6   ERPS P = Minimumof: X   0.98PQ ` or;   t  6    P     X   106SVCS(0.33/tsv)   t where:0  ER P = totalemissionrateofcontaminanti[g/s]P$$  t  6   ERDIFF0 P =0 P $P $diffusionemissionrateofcontaminanti[g/s]* f $ $  t  6   ERPS P =0 soilporosityemissionrate[g/s]!@  $ $  t  6   CS P = massloadingofcontaminantiinsoil[g/cm3] !!  t  6   SA P = areaofemittingsurface[m2] ""  t  6   P P = vaporpressureofcontaminanti[mmHg] ##  t  6   Q P = excavationrate[m3/s] l$$  t  6   SV P =0 volumeofsoiltobeexcavated[m3]F%% $ $  t  6   tsv P =0 timetoexcavatesoilvolume[s] &\ & $ $  t  6 10,000 P = conversionfactor[cm2/m2] &6!'  t  6 1.22x106 P = conversionfactor[cm2 s mmHg/g] '"(  t  6 1.79x109 P =0 conversionfactor[s2 cm mmHg/g](") $ $  t  6   0.980 P =0 P $P $conversionfactor[g/mmHg m3])#* $ $  t  6   106 P =0 conversionfactor[cm3/m3]b*$+ $ $  t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries ,R&- ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section4.1, ,,'. March1993.-(/$$ Ї t Assumptions:0 P Thesoilporespacevaporpressureofcontaminantscanbeapproximatedas  describedinSection4.1ofthecitedsourcedocument. P $P $ MODEL9: t Description:ThermalDesorptionEquation0 t 06t$t$06$6$ER= P (C/1000)(FT/1000)(V/100) $$  t where:0  ER P = emissionrateofcontaminanti[g/s]H $$  t  6   C P = concentrationofcontaminanti[g/g] "^   t  6   FT P = totalfeedrateofmaterialtreated[kg/hr] 8   t  6   V P = percentageofcontaminantivolatilized[%]    t  6   1000 P = conversionfactor[g2/kg g]    t  6   3600 P = conversionfactor[s/hr]    t Source:0  USEPA,EPA451/R93001,Air/SuperfundNationalTechnicalGuidanceStudySeries >z ModelsforEstimatingAirEmissionRatesfromSuperfundRemedialActions,Section3.4, T March1993. $$  t Assumptions:0 P Percentagevolatilizedcanbeapproximatedbasedoncompoundtypeand  desorbertemperatureasdescribedinSection3.4ofthecitedsourcedocument. P $P $